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ANL-7180 /(7\ W ANL-7180
@ D{ MASILR
Argonne JAational Laboratory
CATALOG OF NUCLEAR REACTOR CONCEPTS
Part I. Homogeneous and
Quasi-homogeneous Reactors
Section Y. Reactors Fueled with
Uranium Hexafluoride, Gases, or Plasmas
by
Charles E. Teeter, James A. Lecky,
and John H. Martens
o
| - T
gD FOR ANHOUNCENER
RELEAS
TS5
L Lo ARSTRAGER .
1& ‘E}:‘b L e
I,._—-—" o
X
DISCLAIMER
This report was prepared as an account of work sponsored by an
agency of the United States Government. Neither the United States
Government nor any agency Thereof, nor any of their employees,
makes any warranty, express or implied, or assumes any legal
liability or responsibility for the accuracy, completeness, or
usefulness of any information, apparatus, product, or process
disclosed, or represents that its use would not infringe privately
owned rights. Reference herein to any specific commercial product,
process, or service by trade name, trademark, manufacturer, or
otherwise does not necessarily constitute or imply its endorsement,
recommendation, or favoring by the United States Government or any
agency thereof. The views and opinions of authors expressed herein
do not necessarily state or reflect those of the United States
Government or any agency thereof.
DISCLAIMER
Portions of this document may be illegible In
electronic image products. Images are produced
from the best available original document.
LEGAL NOTICE
This report was prepared as an account of Government sponsored work. Neither the United
States, nor the Commission, nor any person acting on behalf of the Commission:
A. Makes any warranty or representation, expressed or implied, with respect to the accu-
racy, completeness, or usefulness of the information contained in this report, or that the use
of any information, apparatus, method, or process disclosed in this report may not infringe
privately owned rights; or
B. Assumes any liabilities with respect to the use of, or for damages resulting from the
use of any information, apparatus, method, or process disclosed in this report.
As used in the above, ‘‘person acting on behalf of the Commission’ includes any em-
ployee or contractor of the Commission, or employee of such contractor, to the extent that
such employee or contractor of the Commission, or employee of such contractor prepares,
disseminates, or provides access to, any information pursuant to his employment or contract
with the Commission, or his employment with such contractor.
Printed in USA. Price $3.00. Available from the Clearinghouse for Federal
Scientific and Technical Information, National Bureau of Standards,
U. S. Department of Commerce, Springfield, Virginia
ANNOUNCEMENT
)
RELEASED FOR
j STRACTS
IN NUCLEAR SCIENCE ABSTRA
.
ARGONNE NATIONAL LABORATORY
9700 South Cass Avenue
Argonne, Illinois 60439
CATALOG OF NUCLEAR REACTOR CONCEPTS
Part 1. Homogeneous and
Quasi-homogeneous Reactors
Section V. Reactors Fueled with
"Uranium Hexafluoride, Gases, or Plasmas
by
- Charles E, Teeter, James A. Lecky,
and John H. Martens
Technical Publications Department
March 1966
Operated by The University of Chicago
under
Contract W-31-109-eng-38
with the
U. S. Atomic Energy Commission
ANL-7180
Reactor Technology
(TID-4500) ,
AEC Research and
Development Report
CFSTI PRICES
H.C. $500 ; MN 45
THIS PAGE
WAS INTENTIONALLY
LEFT BLANK
Preface.
TABLE OF CONTENTS
Plan of Catalog of Nuclear Reactor Concepts.
List of Reactor Concepts . . . . . . , . .
SECTION V. REACTORS FUELED WITH URANIUM HEXAFLUORIDE,
GASES, OR PLASMAS. . . . . . . « « « + . &
Chapter 1.
Chapter 2.
Chapter 3.
Introduction. . . . . .
Reactors Fueled with Uranium Hexafluoride
Reactors Fueled with Gases or Plasmas
13
37
THIS PAGE
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LEFT BLANK
<
- PREFACE
This report is én additional sectioh in the Catalog of Nuclear Reactor
Concepts that was begun with ANL-6892 and continued in ANL-6909, ANL-7092, and
ANL-7138, As in the previous reports, the material is divided into chapters,
each with text and references, plus data sheets that cover the individual
concepts.: The plan of the catalog, with the report numbers for the sections
already issued, is given on the next page, which is .followed by pages listing
the concepts included in this section. B |
Dr. Charles E. Teeter, formerly employed by the Chicago Operations Office
~at Argonne, Illinois, is now affiliated with the Southeastern Massachusetts
Technological Institute, New Bedford, Mass. Through a consultantship arrange-
ment with Argonne National Laboratory, he is continuing -to help guide the
organization and compilation of this catalog.
We wish to acknowledge the assistance of Miss Ellen Thro in the prepara-
tion of this section.
J.H. M.,
March, 1966
PLAN OF CATALOG OF REACTOR CONCEPTS
General Introduction _ | ~ ANL-6892
Part I. - Homogeneous and Quasi-homogeneous Reactors
Sectioh I. Particulate-fueled Reactors . ANL-6892
Section II. Reactors Fueled with Homogeneous
Aqueous Solutions and Slurries . ANL-6909
Section IITI. Reactors Fueled with Molten-salt
Solutions ANL-7092
Section IV, Reactors Fueled with Liquid Metals ) ANL-7138
Section V. Reactors Fueled with Uranium Hexa- |
fluoride, Gases, or Plasmas This report
Section VI, Solid Homogeneous Rcactors
Part TI, Heterogeneous Reactors
Section 1. Reactors Cooled by Liquid Metals
Section TII. Gas-cooled Reactors
Section III. Organic-cooled Reactors
Section 1IV. Boiling Reactors
Section V, Reactors Cooled by Supercritical Fluids
Section VI. Water-cooled Reactors
Section VII. | Reactors Cooled by Other Fluids
Section VIII. Boiling-waler Reactuors
Section IX. Pressurized-water Reactors
Part III. Miscellaneous Reactor Concepts
REACTOR CONCEPTS DESCRIBED IN THIS REPORT
Name of Reactor
Hexafluoride Thermal Pile
Uranium Hexafluoride Thermal Pile
Uranium Hexafluoride Thermal Pile
Liquid Hexafluoride Pile
Proposed Hanford Circulated-
Hexafluoride Thermal Pile
U233 Hexafluoride Breeder
Hex P-9 Pile (UF6-D20 Pile)
Homogenebus, Circulating Liquid
UF¢ Fueled Pile
Circulating Liquid UFg Pile
Gaseous UFg Fueled, Gas Cooled
Power Pile '
Gaseous UF ¢ Fueled, Gas Cooled
Power Pile |
Water-Cooled, High Flux, UF¢
Fueled Pile
Circulating Gaseous UFg
Fueled Pile
Homogeneous, Circulating
Gaseous UF¢ Fueled Pile
Gaseous UF6-Fue1ed Reactor
Direct Expansion UFg-Fueled
Reactor
Direct Expansion UFg-Fueled
Reactor
UF6-Fue1ed Reactor for
Locomotive Propulsion
* Gaseous UF6 Reactor
UF6 Gas Phase Reactor
Gaseous-Fuel Fast Rreeder Reactor
Gaseous Reactor for Rocket
Propulsion
Cavity Reactor
Fission-plasma Reactor
Plasma Core Reactor
Fizzler Reactor
Fizzler Reactor for Rocket
Propulsion
Chapter No.
2
2
2
2
N
Hha
w W w w w
Data‘Sheet No.
1
,
3
4
Lun
Page
REACTOR CONCEPTS DESCRIBED IN THIS REPORT (Cont.)
Name of Reactor
Gas-Solid Fueled Reactor,
Series for Rocket Propulsion
Cavity Reactor
Gaseous Propulsion Reactor
Vortex Reactor
Coaxial Flow Reactor
Homogeneous Gas Phase¢ Magneto-
hydrodynamic Nuclear Reactor
‘Chapter No.
w w W W W
Data Sheet No.
Page
PART I, HOMOGENEQUS AND QUAST-HOMOGENEQUS REACTORS
SECTION V. REACTORS FUELED WITH URANIUM HEXAFLUORIDE, GASES, OR PLASMAS
Chapter 1. Introduction
This section covers reactors fueled with uranium hexafluoride, either as
a gas or a liquid, and those fueled with other gases (such as vaporized fis-
sile metals) or with plasmas (ionized gases). Although uranium hexafluoride
is normally a solid or a gas (it sublimes at 56.4°C under atmospheric pressufel)
its use as a liquid by keeping the system under pressure has been proposed.
The liquid phase appears above the triple point of 147.3°F and 22 psia. The
critical point is at PC, 45.5 atm; and TC, 446°F.2 The reactors fueled with
UF, are included in Chapter 2. Reactors fueled with other gases or with
6
plasmas are in Chapter 3; in some of these, uranium hexafluoride is the
original form of the fuel.
The UF6-fue1ed reactors might be considered fairly conventional, in that
the liquid or gaseous fuel is in a reactor system resembling those previously
described for reactors fueled with molten salts or metals. The fuel may
either circulate for cooling or be cooled by another material. In the reactors
fueled with gaseous metals or with plasmas, on the other hand, the gaseous fuel,
at extremely high temperatures, mixes with a gas that is both a rocket propel-
lant and the reactor coolant. Sophisticated means are needed both to contain
and later to separate the two gases. Most of the concepts in this section are
for thermal reactors. Another moderator is therefore needed because with
fluorine alone as a moderator the critical mass would be excessive.
The advantages of UF, as reactor fuels were recognized early in the war-
6
time atomic energy program. It has a low cross section for parasitic neutron
capture. Like other fluid fuels, UF, can be used in simple reactor systems
and can be circulated to give heat tg a boiler or other heat outlet. Fuel
fabrication is not necessary, and both fission products and bred fissile
material can be removed by simple means. The gaseous fuels have the added
advantage that they are not limited by structural properties to any minimum
temperature. There are, however, difficulties with the systems described in
this section. Such problems as possible instability, corrosiveness, and
[isslon-product deposition with UF, and the need for special containment
6
methods for gases and plasmas at extremely high temperatures will be covered
in Chapters 2 and 3. Two difficulties common to both types of gaseous reactors
10
are that gases are poor conductors of heat and extremely large volumes are
needed to obtain a critical mass because of the low density of gases.
An early suggestion for the use of uranium hexafluoride as a reactor fuel
was in the concept by Anderson and Brown in 1942,3 They proposed using liquid
UF6°
thereafter. Concepts have been published intermittently since then, although
Several other concepts were advanced during World War II and shortly
no practical development has occured in the United States. Some of the
suggestions published are too incomplete for data sheets to be made. 1In
Russia, a 1ow;power experimental reactor fueled with gaseous UF6 began opera-
tion in 1957.
The reactors fueled with high-temperature gases, such as the vortex and
the plasma reactors, first received attention shortly atter the war, especially
for rocket propulsion. Several concepts have been published; much of this
work deals with the problem of separating the gaseous fuel and the propellant
gas. Work is continuing in this field, but details of some developments are
not available.5
11
References
W.D. Wilkinson, Uranium Metallurgy, Vol. 1, Uranium Process Metallurgy,
p. 553, Interscience Publishers, 1962,
J.W. Arendt, E.W. Powell, and H.W. Saylor, comps. and eds., A Brief
6
H.L. Anderson and H.S. Brown, Liquid UF6 Plant for the Production of
Element 94, CN-362, Metallurgical Laboratory, University of Chicago,
Nov. 27, 1942,
Guide to UF, Handling, K-1323, Union Carbide Nuclear Co., Feb. 18, 1957.
I.K. Kikoin, V.A. Dmitrievsky, Y.T. Glazkov, I.S. Grigoriev, B.G. Bubovsky,
and S.V. Kersnovsky, Experimental Reactor with Gaseous Fissionable Sub-
stance (UF6), Proc. 2nd U. N. Int. Conf, on Peaceful Uses of Atomic
Energy, 9, pp. 528-534, United Nations, N.Y., 1958.
R.S. Cooper, Advanced Nuclear Propulsion, Nuclear News, 7, No. 11, pp. 40-
41, Nov. 1964,
12
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13
Chapter 2. Reactors Fueled With Uranium Hexafluoride
Most of the concepts in this chapter are for thermal reactors. Use of
uranium hexafluoride alone is not practical, and a moderator must be used with
it. Gaseous (helium), liquid (heavy water or fluorocarbons), and solid (beryl-
lium or graphite) moderators have been suggested.
The early concepts for UF6 as a fuel employed either liquid or gaseous
forms. Later, use of the gaseous fuel predominated. The advantages of a gas
as fuel have been given in Chapter 1.
Some problems appear to need further investigation: stability of the
compound under irradiation; corrosion of containment materials, especially
under irradiation; settling out in the reactor of solid UF6, fission pfoducts,
or corrosion products; and the use of a moderator for which a reactor of rea-
sonable size is possible: for example, if heavy water were to be used as has
been suggested, a very large amount wofild be needed.‘
The only reactor reported to have actually operated with UF6 as fuel was
a Russian reactor that operated at low temperature (90°C) and low power (1.5 kW)¢1
The Russian investigators, Kikoin et al., found that the decomposition of the
UF6 could be hindered by adding chlorine trifluoride. No experience on the
stability under radiation at temperatures usual in power reactors has been
reported.
The corrosivity of UF6 toward metals has been investigated, but apparently
not under conditions of irradiation. Heymann and Kelling2 found that the cor-
rosion rates at 80°C are low for nickel, copper, Monel, aluminum, alloy steels,
and titanium alloys. For use at high temperatures, high-purity nickel and
Monel appear to be best, Langlois3 studied corrosién by UF6 at high tempera-
tures. High-purity nickel has the lowest corrosion rates above 800°C, and
these rates are compatible with industrial uses. Between 550° and 700°C,
however, corrosion of nickel and Monel by penetration along crystalline bound-
aries prohibits the use of these metals in this temperature range. Nickel of
the highest purity, in which impurities responsible for intergranular attack
are eliminated, should have greatly improved corrosion resistance. Dry UF6
is normally contained in nickel or Monel. Lane4 points out that the stability
under irradiation of the protective film on these metals has not been investi-
gated. _ _
In 1947, Hull5 described several concepts and discussed different aspects
of using UF, as fuel. He listed many advantages, most of which have been given
6
here already. Others he noted are: remote operation permits low-decontamination
14
ceparation, with consequent simplified processing; and elimination of cooling
permits a low inventory. He suggested hydrogen fluoride (b.p., 19.4°C),
deuterium fluoride, and fluorocarbons as liquid solvent-moderators for homo-
geneous reactors. Helium or fluorocarbons would be coolants; water or liquid
metals would have to be kept separate from the UF6 because of the vigorous
reactions that would occur on contact between them and the fuel. Graphite
reacts so vigorously with UF, that it also would have to be separated. For
6
containment materials, he suggested beryllium or nickel; aluminum or magnesium
could be used if the problem of attack by UF6 could be solved. Areas in which
he thought investigation was needed are: corrosion of metals by uranluw liesa=-
fluoride and fluorine; decomposition of UF, by fission-product fluorides, witLh
6
or without solvents; and heat transter by radiation and conduclivu through
is formation of gas bubbles
gaseous UF A possible problem with liquid UF
6°
that might cause instability. °
In 1962, Wethington6 proposed that research be carried out on a reactor
fueled with a solution of uranium hexafluoride in a fluorocarbon. He cited
the Russian experience and the work of others to show that although there
would be some decomposition of UF6 under radiation it could be controlled and
it would be no worse than that uf other compounds used in reactor technology.
The fluorocarbons were suggested as promising moderators because published
information indicates that they have good radiation stability. More investi-
gation, however, would be needed on Lfie coucept,
As mentioned in Part I, Section I, of this catalog, Kerze has suggested
that CaF2 particles might be fluidized with.a mixture of uranium hexafluoride
and tetrafluoromethane (CF4) to give a gaseous suspension. The feasibility of
such a system would depend upon the mixture having sufficient moderating pro-
perties, -
Another concept with uranium hexafluoride as a gaseous fuel has been dis-
cussed in Part I, Section I. Halik et al. proposed fluidizing Fine particles
of beryllium oxide moderator by the fuel gas.
Reactors Fueled With Liquid Uranium Hexafluoride
In 1942, Anderson and Brown,7’8 of the Metallurgical Laboratory of the
University of Chicago, suggested a reactor fueled with liquid uranium hexa-
fluoride, as well as two variants of the original design. The reactor would
be a breeder for producifig plutonium. 1In the original design, the fuel-
coolant-fertile material is natural or enriched 1iquid>UF6.- The fuel circulates
through tubes in a moderator of graphite or heavy water and goes to an external
15
heat exchanger. The tubes are of uranium lined fiith nickel dr other corroéion-
resistant metal of low neutron-absorption cross section. A power of more than
100 MW(t) was expected. In the first variant, the central portion of the
graphite matrix contains uranium rods, which are cooled by helium passing be-
tween the rods. At the periphery of the matrix are aluminum tubes containing
liquid UF,, which passes to an external heat exchanger. Breeding occurs in this
6’
outer region, which also serves as a reflector for the inner section of rods.
In the second variant, there is a central spherical void, filled with heavy
water, in the graphite matrix. The UF, circulates through tubes that are im-
bedded in the graphite and pass througg the heavy water. A power of more than
100 MW(t) was expected.
Two 1943 concepts from the Metallurgical Laboratory, University of Chicago,
are a Liquid Hexafluoride Pile and the Proposed Hanford Circulated-Hexafluoride,
Thermal Pile.9 Both are rated at 390 MW(t). 1In the first, the liquid UF6
circulates through tubes of aluminum in a graphite moderator and out to a heat
exchanger. This concept is a burner. 1In the second concept, the fuel circu-
lates through tubes, immersed in 25 tons of heavy water surrounded by a graphite
reflector, to an external heat exchanger. It is a breeder, with the fuel and
fertile material being natural uranium moderated by heavy water.
In the U233 Hexafluoride Breeder,10 suggested by Metallurgical Laboratory
staff members in 1944, a fluorocarbon is utilized to dissolve U233Fé, and
thorium is the reflector-breeding blanket. The fuel circulates in tubes through
the cylindrical core. The power is 100 to 200 MW(t).
A 1944 concept by Anderson is the Hex P-9 Pile (UF6-D
would require 686 tons of liquid UF6(”Hex"), probably highly enriched for a
2O pile).8’11’12 This
burner and natural uranium for a breeder, with 63 tons of heavy water ("P-9'")
as moderator. The fuel circulates through tubes in the moderator and out the
top to a heat exchanger. Temperature limits to prevent both solidification
and vaporization of the UF, are 75°C minimum and 150°C maximum.
Among the concepts described by Hull in 19475 were two for liquid UF6
fuel. 1In one, the fuel is.liquid UF, dissolved in either a liquid fluorocarbon
6
or deuterium fluoride. The fuel circulates for heat exchange and removal of
fission products. It has thorium tetrafluoride as fertile material. 1In the
second concept, the fertile material, thorium tetrafluoride, is present as a
fine powder within beryllium cylinders in a graphite bed.
16
Reactors Fueled With Gaseous Uranium Hexafluoride
In 1947, Hull5 described the use of gaseous uranium hexafluoride, pointing
out the advantages of the fluid fuel, and he described concépts originated by
staff members of the Clinton Laboratories (now QOak Ridge National Laboratory).
A preliminary study on such piles had been published earlier in the same year
by Hull and Miles.13
In one design, the fuel, U233 or U235 in UF6, is contained in porous
beryllium tubes surrounded by impervious beryllium tubes. The pores are for
trapping fission products. The tubes are within a graphite moderator core that
is either in the form of rods in the center ¢f a triangular lattice ot tuel
tubes or as annular tubes around them. The coolant, helium, circulates through
the spaces in the core and out to a heat exchanger. A blanket of thorium
powder in beryllium tubes within a graphite bed is the fertile material. Bred
fissile material is leached out of the fuel by slowly circulating fluorine
through the bed. The porous design of the fuel tubes, intended to facilitate
trapping of fission products, allows the products to be removed from the UF6
without chemical processing. This design was for a power of 96 MW(t).
In a modification of this design, the fuel circulates slowly through
aluminum tubes outside the reactor. These tubes have large pores that do not
trap the fission products. Thus removal of fission products is continuous,
permitting better neutron cconomy. Bccausc of their low cost, these aluminum
tubes can be discarded instead of being reprocessed, but their use results in
lower power potential. The power is 50 MW(t).
In a high-flux pile, the water coolant flows in an annulus between porous
233 or U235 as
aluminum rods and beryllium cylinders. The rods contain U
gaseous uranium hexafluoride. Water cooling of the rods, according to the
author, gives a high power output--32 MW(t)--but at a temperature too low for
economic value in generation of electrical power. The moderator would be either
water or beryllium. A reflector-blanket, like that in the previous design,
permits breeding.
The originators believed that the uranium bred in the reactor could be
removed fairly simply from the blanket of the finely powdered thorium fluoride
contained in beryllium tubes. A hot mixture of helium and fluorine flowing
through the powder would convert the products to fluorides. If the powder were
fine enough and the temperature high enough, the PaF5 and UF6 could diffuse
through the beryllium, be volatilized at the surface, and be carried away by
circulating gas. The UF, could be separated in a fractionating column con-
6
. . 2
tinuously as soon as the proactinium decays to U 33.
Ll
17
Two other concepts described were for reactors in which gaseous UF6'cir-
culates outside the reactor for removal of fission products and, presumably,
for heat exchange. Both would operate at 230°C or higher. This temperature
would avoid the need for excessive pressure. In one desigfi, the fuel circu-
lates through holes in a cylinder of beryllium moderator. The authors stated
that fission products would settle out of the gas onto surfaces within the -
reactor, but using the gaseous form of UF6 avoids the problem of gas. bubbles
that would occur with liquid UF In the other design, the reactor is homo-
geneous, with the moderator beigg a gas, helium or carbon tetrafluoride
(tetrafluoromethane). The operating pressure is 100 atm. The authors specify
a spherical reactor with a diameter of 17 meters, but they stated that it was
too large to be considered at that time. Breeding with a blanket would be
possible, but the blanket would have to be extremely large.
A 1947 suggestion by Goodman14 for a reactor fueled with gaseous UF6
included the use of fluorine to stabilize the UF6 and to act as additional
moderator. The fuel either circulates to an external heat exchanger or re-
mains fixed and is cooled by a coolant such as liquid metal passing through
coils.
In 1953 Kerner proposed the use of the direct expansion of UF6 in an
internal-combustion engine, a turbine, or a reciprocator, The gas is
briefly compressed to supercriticality with a piston; it heats up and pushes
back the piston. The gas returns to the core through a heat exchanger and a
pump.
Reactor concepts in which this direct expansion were utilized were ad-
vanced in 1953 by ‘Fortescue]'6 and in 1957 by Clasen..’17 In the 1953 concept,
the moderator is molten beryllium fluoride surrounding fuel tubes in a cylin-
drical nickel calandria. The reactor is under a pressure of 20 atm.. Cadium
absorbers in the heat exchangers were suggested for control of criticality
outside the core. 1In the 1957 concept, the fuel is within a beryllium core;
the turbine also is to be made of beryllium as much as possible. A graphite
reflector surrounds core and turbine. A blanket of U238F6 is suggested if
breeding is desired. A fast reactor is suggested as an alternative, but no
details are given.
235
The expansion of gaseous U ~"F, is the basis for another reactor, for
6
which few details are given, in which a piston compresses the gas fuel in each
18- , Lo .
end of a cylinder.'8 20 The compression causes criticality, and the gas ex-
pands to drive the piston to the opposite end, where the gas at that end ex-
pands. Thus a reciprocating action of the piston results. Each end of the
18
cylinder is surrounded by a moderator and reflector. Direct conversion of the
piston motion into electrical action by use of electromagnefic induction was
proposed° The application of the concept to locomotives has been suggested, and
in 1955 the USAEC awarded a contract for the study of a nuclear-powered recipro-
cating engine for locomotive propulsion to the Baldwin-Lima-Hamilton Corporation
and the Denver & Rio Grande Railroad.20 The chief problems visualized were in
startup and in handling UF
6‘
The only UF6-fue1ed reactor to be built and operated is the Russian low-
power [1.5 kW(t) ] experimental reactor, fueled with gaseous UF6. It went
1,21 ; ; . . .
’ Russian investigators reported that the reactor operated
critical in 1957.
satisfactorily. There was a pressure drop and a decrease in reactivity at a
higher power level, which was attributed to dissociation of the UF6 under 1r-
radiation. Adding chlorine trifluoride permitted stable operation. The fuel
is highly enriched uranium hexafluoride, the moderator is beryllium, and the
reflector is graphite. The fuel is within channels formed from aluminum tubes,.
Criticality is achieved by increasing the pressure. Control rods are provided,
The authors suggest that improved methods of plutonium breeding might be pos-
sible with the UF6 reactor. Some plutonium fluorides are not volatile, and
plutonium hexafluoride, which has a high vapor pressure, is unstable. Thus
special traps in the fuel-coolant system might be used to collect plutonium
fluorides. ,
A 1958 concept by Baron22 was for a circulating-fuel converter utilizing
slightly enriched uranium in the gaseous fuel as both fuel and fertile material.
The fuel flows by natural circulation through double-wall aluminum tubes set
within graphite blocks in the core; helium, the intermediate coolant, is in the
annulus between the tube walls and in an external heat exchanger to which the
fuel circulates. The fuel leaves the corc at 900°F. To maintain sufficient
fuel circulation, a core height of .25 feet is specified. The power is 35 MW(e).
9
Hammitt,"3
in 1960, described a concept for a fast breeder reactor in which
the UF6 fuel and the sodium coolant flow through parallel tubes made from a
nickel alloy. A blanket of fertile material surrounds the core. The power
given is 300 MW(t).
Status
vThefe appear to have been no sustained developmental programs leading to
reactor experiments for reactors fueled with uranium hexafluoride. The early
interest in uranium hexafluoride as a reactor fuel has resulted in compara-
tively few concepts and, aside from the low-power Russian reactor, apparently
no practical development. Recent concepté have been few. Questions of practi-
cal feéctor operation, such as stability and corrosivity of UF6 under operating
conditions of a power reactor, are not yet clarified.
20
THIS PAGE
WAS INTENTIONALLY
LEFT BLANK
DATA SHEETS
REACTORS FUELED WITH URANIUM HEXAFLUORIDE
21
22
THIS PAGE
WAS INTENTIONALLY
LEFT BLANK
23
No. 1 Hexafluoride Thermél Pile
Metallurgical Laboratory, University of Chicago
References: CN-362; U.S. Patent 2,990,354,
Originators: H.L. Anderson and H.S. Brown.
Status: Proposal, November 1942; pétent issued, 1961.
Details; Thermal neutrons, steady state, breeder, for production of Pu. Fuel-
coolant-fertile material: natural or enriched U in liquid UF6' Moderator:
graphite or DZO' Core arrangement: liquid UF6 circulates through tubes in
moderator matrix to external heat exchanger. If moderator is graphite blocks,
tubes are of U lined with Ni or other corrosion-resistant metal of low neutron-
absorption cross section. If moderator is D20, tubes are of U lined with alloys
of metals of low neutron-absorption cross section, such as Ni, Be, or Mg. With
D20, 223 tubes, 8 cm ID, in cylindrical core 3.31 m long, 3.6 m diameter; l.Q82
reproduction factor. With graphite, 1700 tubes, 4 cm ID, 8.30 cm long. Bred
Pu can be recycied as fuel or separated chemically., Control: Cd or boron
steel rods. Power: probably more than 100.MW(t). Breeding ratio: 1.029.
Code: 0312 12 31110 41 612 732 81X11 941 104
14 42 733 81X12
No. 2 Uranium Hexafluoride Thermal Pile
"Metallurgical Laboratory, University of Chicago
Referenqes: CN-362; U.S. Patent 2,990,354,
Originators: H.L. Anderson and H.S. Brown.
Status: PrOposal, November 1942;'patént issued, 1961.
Details: Variant of concept in Data Sheet No. 1. Central portion of graphite
matrix contains U rods cooled by helium, which passes through spaces between
rods. At.fieriphery of matrix, Al tubes concain:circulating:1iquiq-UF6;thich::“
passes to external heat exchanger. .Outer g'raphite-—UF6 system acts as reflector
to U-rod section and also serves as breeding section, from which Pu can be
extracted, |
Code: 0312 12 31110 41 612 732 81X11 941 109
31716 42 733 81X12
No. '3 Uranium Hexafluoride Thermal Pile
Metallurgical Laboratory, University of Chicago
References: CN-362; U.S. Patent 2,990,354
Originators: H.L. Anderson and H.S. Brown.
Status: Proposal, November 1942; patent issued; 1961.
Details: Variant of concept in Data Sheet No. 1. Graphite matrix has central
sphericaIFVOid filled with D,0. Al or U tubes imbedded in graphite pass
2
through D20° UF6 circulates through tubes. _
Cnde: 0312 12 31110 41 612 732 81X1l 941 LUY
14 42 733 81X12 |
No. 4 Liquid Hexafluoride Pile
Metallurgical Laboratory, University of Chicago
Reference: Unpublished report, 1943.
Originators: Staff members.
Status: Preliminary proposal, 1943,
Details: Thermal neutrons, steady state, burner. Fuel-coolant: liquid UF6°
Moderator-reflector: graphite. Fuel circulates through 170 Al tubes surrounded
by graphite to external heat exchanger. Secondary coolant: HZOa Moderator
would probably have to be cooled by subsidiary water cycle. Fraction of fuel
continuously withdrawn and put through evaporator for removing fission products.
Core requires 15 tons of UF, and 25 tons of graphite. Fuel temperature in core:
6
194°F; temperature rise in center tube: 108°F. Power: 390 MW(t).
Code: 0313 12 31110 44 612 711 8XXXX 921 104
No. 5 Proposed Hanford Circulated-Hexafluoride Thermal Pile
Metallurgical Laboratory, University of Chicago
Reference: Unpublished report, 1943.
Originators: Staff members.
Status: Proposal, 1943.
Details: Thermal neutrons, steady state, breeder. Fuel-coolant-fertile
material: natural U in liquid UF_, which circulates to external heat ex-
239 238 6
25
changer. Pu bred from U . Moderator: D,0. Reactor: vertical cylinder.
2
Fuel circulates through core in tubes of Al, Be, Mg, or U. Tubes immersed in
25 tons of DZO surrounded by graphite reflector, UF6 enters at 176°F and
leaves at 248°F. Operating pressure: 250 psia. Power: 390 MW(t).
Code: 0312 14 31110 41 612 732 8XXXX 921 104
No. 6 U233 Hexafluoride Breeder
Metallurgical Laboratory, University of Chicago
Reference: Unpublished report, 1944,
Originators: Staff members.
Status: Proposal, 1944, -
Details: Thermal neutrons, steady state, breeder. Fuel-coolant-moderator:
U233 in UF, dissolved in fluorocarbon; circulates to external heat exchanger.
6
Fertile material: Th reflector-breeding blanket., Fuel circulates through
tubes in cylindrical reactor. Temperature rise, fuel inlet to outlet: 90°F.
Power: 100 to 200 MW(t).
Code: 0312 18 31209 45 622 7X6 8XXXX 931 101
26
No. 7 Hex P-9 Pile (UF,-D,O Pile)
|8
2
Metallurgical Laboratory, University of Chicago
References: CE-1150; CE-1074; U.S. Patent 2,990,354, June 27, 1961.
Originator: H.L. Anderson.
Status: Preliminary design, 1944,
Details: Thermal neutrons, steady state, burner or breeder. Fuel-coolant:
686 tons liquid UF6 (465 tons U). U, probably highly enriched in U235 for
burner, probably natural for breeder. Bred Pu could be recycled as fuel.
Moderator: 63 tons D20. Fertile material: U238
fuel circulated by thermal syphon into reactor at bottom, through pipes in
in UFfi. Core arrangement:
core, and out at_top to external heat exchanger. Cold fluid returned to
bottom of core. Maximum temperature: 150°C, to avoid need for high pressure
to keep UF, liquid; minimum temperature: 75°C, to prevent solidification.
Pressure: 6150 psi, to prevent vaporization. Control: control rod and safety
rod of Cd or boron steel; high rate of change of density and high temperature
coefficient of expansion of UF6° Power: 600 MW(t). Specific power: 1300-
1600 kW/ton UF6 at AT of 75-130°C; 550-650 kW/ton UF at AT of 75-105°C.
Code: 0312 14 31110 41 612 711 81X11 9XX 104
0313 44 732 81X12
46 84689
No. 8 Homogeneous, Circulating Liquid UF,_ Fueled Pile
Clinton Laboratories
Reference: MonN-336.
Originators: Staff members.
Status: Preliminary proposal, 1947.
Details: Thermal neutrons, steady state, could be used for power production,
breeding, or producing high flux. Fuel-coolant-moderator: U235 in liquid UF6
dissolved in either liquid fluorocarbon or DF. Fertile material: ThF Fuel
solution circulates for continuous removal of fission products and foraheat
exchange. Reactor would operate at 100°C and, with DF moderator, 15 atm. Con-
tainment material would probably be Ni rather than Al or Mg, despite the loss
in breeding gain.
Code: 0311 17 31209 44 622 7X6 8XXXX 9XX 101
0312 18 31213
No. 9 Circulating Liquid UF, Pile
(o
< Clinton Laboratories
Reference: MonN-336.
Originators: Staff members.
Status: Preliminary concept, 1947.
Details: Thermal neutrons, steady state, could be used for power production,
breeding, or production of high flux. Fuel-coolant: U235 in liquidlUFG;.
could circulate t6 external heat exchanger. Moderator: Be. Reflector-
breeding blanket: 'I'hF4 as fine powder in Be cylinders in graphite bed. Con-
tainment materials: Be, Al, or Mg. Pressure: & atm. Specific power: .about
1 kW/kg UF,.
Code: 0311 15 31110 44 612 776 8XXXX 941 104
0312
27
28
No. 10 Gaseous UF, Fueled, Gas Cooled Power Pile
6—— . , .
Clinton Laboratories
Reference: MonN-336.
Originators: Staff members.
Status: Preliminary design, 1947.
Details: Thermal neutrons, steady state, could be used for power production,
U233 or U235
breeding, or production of high flux. Fuel: in gaseous UF
6'
Coolant: helium. Moderator: graphite. Reflector-breeding blanket: fine
powder of ThF, in Be cylinders in graphite bed. Bred fuel removed by slow ©.°