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NAT_MSBRdesign.txt
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NAT_MSBRdesign.txt
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1000
THE DESIGN AND PERFORMANCE
FEATURES OF A SINGLE-FLUID
MOLTEN-SALT BREEDER REACTOR
E. S. BETTIS and ROY C. ROBERTSON Reactor Division
KEYWORDS: molten-salt re-
actors, design, performance,
economics, uranium-233, pow-
er reactors, fuels, MSBR, cost,
fuel cycle
Oak Ridge National Labovatory, Oak Ridge, Tennessee 37830
Received August 4, 1969
Revised October 2, 1969
A conceptual design has been made of a single-
fluid 1000 MW(e) Molten-Salt Breeder Reactor
(MSBR) power station based on the capabilities of
present technology. The reactor vessel is ~22 ft
in diameter X 20 ft high and is fabricated of
Hastelloy-N with graphite as the wmoderator and
reflector. The fuel is 23U carvied in a LiF-BeF ,-
ThFy mixture which is molten above 930°F. Tho-
rium is converted to “®U in excess of fissile
burnup so that bred material is a plant product.
The estimated fuel yield is 3.3% per year.
The estimated construction cost of the station
is comparable to PWR total construction costs.
The power production cost, including fuel-cycle
and graphite replacement costs, with private
utility financing, is estimated to be 0.5 to 1 mill/
kWh less than that for bresent-day light-water
reactors, largely due to the low fuel-cycle cost
and high plant thevmal efficiency.
After engineering development of the fuel puri-
fication processes and large-scale components, a
practical plant similar to the one described here
appears to be feasible.
INTRODUCTION
The objective of this design study is to investi-
gate the feasibility of attaining low-cost electric
power, a low specific inventory of fissile material,
and a reasonably high breeding gain in a molten-
salt reactor. As discussed by Perry and Bauman®
a molten-salt reactor can be designed as either a
breeder, or, with relatively few major differences
other than in fuel processing, as a converter. This
particular design study is confined to the single-
fluid Molten-Salt Breeder Reactor (MSBR).
190
NUCLEAR APPLICATIONS & TECHNOLOGY
The conceptual design of the MSBR plant was
made on the basis that the technology required for
fabrication, installation, and maintenance be gen-
erally within present-day capabilities. Major de-
sign considerations were keeping the fuel-salt
Inventory low, accomodating graphite dimensional
changes, selection of conditions favoring graphite
life, and providing for maintainability.
The facilities at an MSBR power station can be
grouped into the following broad categories: (a)
the reactor system which generates fission heat in
a fuel salt circulated through primary heat ex-
changers; (b) an off-gas system for purging the
fuel salt of fission-product gases and colloidal
noble metal particulates; (c) a chemiecal proces-
sing facility for continuously removing fission
products from the fuel salt, recovery of the bred
*3U, and replenishment of fertile material; (d) a
storage tank for the fuel salt which has an after-
heat removal system of assured realiability; (e) a
coolant-salt circulating system, steam generators,
and a turbine-generator plant for converting the
thermal energy into electric power ; and (f) gen-
eral facilities at the site which include condensing
water works, electrical switchyard, stacks, con-
ventional buildings, and services. These cate-
gories are not always clearly defined and are
closely interdependent, but it is convenient to
discuss them separately. The reactor, and its
related structures and maintenance system, the
drain tank, the off-gas system, and the chemical
processing equipment, are of primary interest.
The steam turbine plant and the general facilities
are more or less conventional and will be dis-
cussed only to the extent necessary to complete
the overall picture as to feasibility and costs of an
MSBR station.
In a single-fluid MSBR the nuclear fuel is 2*°U
(or other fissile material) carried in a lithium-T7-
fluoride, beryllium-fluoride, thorium-fluoride salt.
The mixture is fluid above ~930°F and has good
flow and heat transfer properties and very low
VOL. 8 FEBRUARY 1970
Bettis and Robertson
vapor pressure. This salt is pumped in a closed
loop through a graphite-moderated and reflected
core where it is heated to ~ 1300°F by fissioning
of the fuel. It then flows through heat exchangers
where the heat is transferred to a circulating heat
transport salt. This fluid, in turn, supplies heat to
steam generators and reheaters to power a con-
ventional high-temperature, high-pressure steam
turbine-generator plant. The thorium in the flu-
oride fuel-salt mixture is converted to **Uat a
rate in excess of the fuel burnup so that fissile
material, as well as power, is a valuable product
of the plant.
A low specific inventory is obtained by design-
ing the MSBR to operate at a high reactor power
density with a minimum of fuel salt in the circu-
lating system. The concentration of fissile-fertile
material in the salt results from a compromise
between keeping the inventory low and achieving a
higher breeding gain. High performance depends
on keeping the neutron parasitic absorptions low
and fuel losses to a minimum. The Li and Be in
the fuel salt are good neutron moderators, but
their concentrations are relatively low in fluoride
salts and additional moderation is needed. Graph-
ite is the most satisfactory moderator and re-
flector for the MSBR. However, radiation affects
the graphite and its useful life varies nearly in-
versely as the maximum power density in the
core. The radiation damage effect is also in-
creased by higher temperatures. Selection of a
power density is thus a balance between a low fuel
inventory and the frequency with which the graph-
ite must be replaced.
The optimization studies which equate the sev-
eral factors mentioned above are described by
Scott and Eatherly.?* These studies indicate that
an average core power density of 22.2 kW/liter
results in a useful graphite life of ~ 4 years, which
is the operating condition used in this design
study. Thus, the reactor design must provide for
periodic replacement of the core graphite with
minimal plant downtime and complexity of mainte-
nance equipment.
To attain a high nuclear performance it is
necessary to maintain low concentrations of Pa
and %°Xe in the high flux region of the core.
The protactinium is kept low by processing a
small side stream of the salt for removal of this
nuclide and other fission products. By integral
processing on-site a minimum inventory of fuel
salt is involved in transport and storage. The
xenon is removed by helium-sparging the fuel salt
on a few-second cycle; the core graphite is also
sealed to decrease the rate of diffusion of the Xe
into the pores of the graphite. The plant design
therefore includes the auxiliary systems to re-
move the nuclear poisons and the bred fissile ma-
NUCLEAR APPLICATIONS & TECHNOLOGY VOL. 8
MSBR DESIGN AND PERFORMANCE
terial from the salt, to purge the fission-product
gases, and to store or dispose of the radioactive
waste products; Whatley et al.,’ and Perry and
Bauman'® treat the subject of salt processing and
estimate fuel-cycle costs.
Although the economic performance of a 2000
MW (e), or larger, MSBR station would be signifi-
cantly better than that of smaller sizes, a plant
with a net electrical output of 1000 MW(e) was
chosen for this study because it permitted more
direct comparison with the results of other
studies. A steam-power cycle with 1000°F and
3500-psia turbine throttle conditions, with single
reheat, was selected because this was representa-
tive of current practice and because it afforded a
high overall plant thermal efficiency of ~ 44%.
The MSBR is adaptable to other steam conditions
and to additional reheats if future developments
lead in this direction.
All portions of the systems in contact with
salts are fabricated of Hastelloy-N. When this
material is modified with ~1% titanium or hafnium
to improve resistance to radiation embrittlement,
as described by McCoy et al.,* it has good high-
temperature strength and excellent resistance to
corrosion. No exothermic reactions of concern
result from mixing of the fuel and coolant salts
with each other or with air or water. It is im-
portant to keep water and oxygen out of the salts
in normal operation, however. The reactor graph-
ite is a specially developed type having very low
salt and gas permeability and good resistance to
radiation damage. The salt composition is a com-
promise between the nuclear and physical proper-
ties, chemical stability, etc., as discussed by
Grimes.? Some selected physical properties of the
materials important to the design study are shown
in Tables I, II, and III.
The performance features of the plant, in terms
of breeding gain, graphite life, thermal efficiency,
and the net cost to produce electric power, are all
reported here on the basis of normal full-load
operation at 80% plant factor. Very preliminary
review of the various modes of start-up and shut-
down, partial-load operation, etc., has not dis-
closed any major problem areas, however.
PLANT DESCRIPTION
A simplified flow diagram of the primary and
secondary-salt circulating systems is shown in
Fig.1. The fluoride fuel-salt mixture is circulated
through the reactor core by four pumps operating
in parallel.? Each pump has a capacity of ~ 14 000
a Flow sheet does not show duplicate equipment.
FEBRUARY 1970 191
Bettis and Robertson
TABLE 1
Properties of the Primary and Secondary Salts Used in
Conceptual Design Study of MSBR 1000- MW(e) Station
Primary Secondary
Salt Salt
Components LiF- BeF,- ThF,-UF, NaBF,-NaF
Composition, mole% 71.6-16-12-0.4 92-8
Molecular weight,
approximate 64 104
Liquidus temperature,
°F 930 725
Density, 1b/ft’ 205 (at 1300°F) 117 (at 988°F)
Viscosity, 1b/(ft h) 16.4 (at 1300°F) 2.5 (at 900°F)
Thermal conductivity,
Btu/(h ft °F) 0.7 to 0.8 0.27
Heat capacity,
Btu/(1b °F) 0.32 0.36
Vapor pressure at
1150°F, Torr (mm Hg) <0.1 252
gal/min and circulates the salt through one of four
primary heat exchangers and returns it to a com-
mon plenum at the bottom of the reactor vessel.
Use of four pumps and heat exchangers corres-
ponds to a pump size which represents a reason-
able extrapolation of the Molten-Salt Reactor
Experiment (MSRE) experience.
Each of the four coolant-salt circuits has a
pump of 22 000-gal/min capacity which circulates
the coolant salt through a primary heat exchanger
located in the reactor cell and then through steam
generating equipment installed in an adjacent cell.
The reactor can continue to operate although at
reduced output, if not all of the coolant salt pumps
are operative.
A plan of the reactor plant is shown in Fig. 2;
‘an isometric view and a sectional elevation are
presented in Figs. 3 and 4.
The reactor cell is ~62 ft in diameter and 35 ft
deep. It houses the reactor vessel, the four pri-
mary heat exchangers, and four fuel-salt circu-
lating pumps. The roof of the cell has removable
plugs over all equipment which might require
maintenance. The reactor cell is normally kept at
a temperature of ~ 1000°F by electric heater
thimbles to ensure that the salts will remain
above their liquidus temperatures. The estimated
maximum heating load is ~2500 kW. This
““furnace’’ concept for heating is preferred over
trace heating of lines and equipment because it
ensures more even heating, heater elements can
be replaced without reactor shutdown, there is no
need for space coolers inside the cell, and bulky
thermal insulation that would crowd the cell and
require removal for maintenance and inspection is
eliminated.
192 NUCLEAR APPLICATIONS & TECHNOLOGY
MSBR DESIGN AND PERFORMANCE
TABLE II
Nominal Values for Properties of MSBR Graphite
Density, 1b/ft> at room temperature 115
Bending strength, psi 4000-6000
Young’s modulus of elasticity, psi 1.7 x 10°
Poisson’s ratio 0.27
Thermal expansion, per °F 2.3 X 10°°
Thermal conductivity, Btu/(hr ft °F)
(1340°F) 35-42
Electrical resistivity, 2-cm 8.9-9.9 x 107*
Specific heat, Btu/(1b °F) at 600°F 0.33
Btu/(1b °F) at 1200°F 0.42
Biological shielding for the reactor cell is pro-
vided by reinforced concrete. The walls of the
reactor cell also furnish double containment for
the fuel-salt systems. Two thicknesses of carbon
steel plate form inner and outer containment ves-
sels, each designed for 50 psig, and also provide
gamma shielding for the concrete. Nitrogen gas
flows between the plates in a closed circulating
loop to remove ~3 MW(th) of heat. Double bellows
are used at all cell penetrations. The normal cell
operating pressure is ~ 26 in. Hg abs.
High-temperature thermal insulation is at-
tached to the inside of the containment membrane
to limit heat losses from the reactor cell. The
inside surface of the insulation is covered with a
thin stainless-steel liner to protect the insulation
from damage, to act as a radiant heat reflector,
TABLE III
Selected Physical Properties of Hastelloy-N
Nominal Chemical Composition of
Modified Alloy for Use in MSBR® wt%
Nickel 75
Molybdenum 12
Chromium 7
Iron 4
Titanium 1
Other 1
At 80°F At 1300°F
Density, 1b/ft* ~553 ~553
Thermal conductivity, Btu/(h ft °F) 6.0 12.6
Specific heat, Btu/(1b °F) 0.098 0.136
Thermal expansion, per °F 5.7 X 107%| 9.5 x 107°
Modulus of elasticity, psi 31 x10° | 25 x 10°
Electrical resistance, Q-cm 120.5%107° 126.0x107¢
Approximate tensile strength, psi 115 000 75 000
Maximum allowable design stress, psi 25 000 3 500
Maximum allowable design stress,
bolts, psi 10 000 3 500
Melting temperature, °F ~2 500 ~2 500
“The exact composition may be different from the nominal values
given here, as discussed by McCoy et al.*
VOL. 8 FEBRUARY 1970
MSBR DESIGN AND PERFORMANCE
Bettis and Robertson
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193
FEBRUARY 1970
VOL. 8
NUCLEAR APPLICATIONS & TECHNOLOGY
Bettis and Robertson
Fig. 2.
and to provide a clean, smooth surface for the
interior.
The stainless-steel ‘‘catch pan’’ at the bottom
of the reactor cell, shown in Fig. 4, slopes to a
drain line leading to the fuel-salt drain tank lo-
cated in an adjacent cell. In the very unlikely
event of a major salt spill, the salt would flow to
the tank. A valve is provided in the drain line to
isolate the tank contents from the cell during nor-
mal conditions and to permit pressurizing the
drain tank for salt transfer.
The four rectangular steam-generating cells
are located adjacent to the reactor cell. These
house the secondary-salt circulating pumps, the
steam generator-superheaters, and the reheaters.
The cell construction is similar to that of the re-
actor cell but only a single containment barrier is
194 NUCLEAR APPLICATIONS & TECHNOLOGY VOL. 8
MSBR DESIGN AND PERFORMANCE
Plan view of MSBR cell complex for 1000 MW(e) power station.
required and heavy steel plate is not needed for
shielding the concrete. The 40-psig design pres-
sure would accommodate leakage of steam into the
cell.
Other adjacent cells provide for storage of the
fuel salt, for storage of spent reactor core as-
sembly, and for other radioactive equipment re-
moved for maintenance.
Through careful quality control of materials
and workmanship, the reactor loops containing
fission products would have a high degree of
integrity and reliability in preventing escape of
radioactive materials from the system. The cool-
ant-salt system will operate at a slightly higher
pressure than the fuel salt so that any leakage at
heat exchanger joints would be in the direction of
the fuel salt. The coolant-salt system would be
FEBRUARY 1970
Bettis and Robertson
Fig. 3.
Cutaway perspective of MSBR reactor and steam cells.
MSBR DESIGN AND PERFORMANCE
(1) Reactor, (2) Primary heat exchangers,
(3) Fuel-salt pumps, (4) Coolant-salt pumps, (5) Steam generators, (6) Steam reheaters, (7) Fuel-salt
drain tank, (8) Containment structure, (9) Confinement building.
provided with rupture disks to prevent steam
pressure from being transmitted to the fuel salt
via the coolant-salt system. In addition to the
double containment around all fuel-salt equipment,
mentioned previously, the building covering the
reactor plant is in itself a sealed structure to act
as a confinement for airborne material.
REACTOR
The MSBR reactor core design is based on a
maximum allowable neutron dose to the core
graphite of ~3 X 10°®> n/cm? (for E > 50 keV). The
average core power density is ~ 22 kW/liter,
NUCLEAR APPLICATIONS & TECHNOLOGY VOL. 8
affording a useful core graphite life of ~4 years,
a fuel yield of ~3.3% per year, and a compounded
fuel doubling time of ~ 21 years. These and other
data are given in Table IV. The dimensions of the
reactor were obtained through nuclear physics op-
timization studies discussed by Perry and Bau-
man."
The coefficient of thermal expansion of Has-
telloy-N is about three times that of the graphite.
As a result, the clearances inside the reactor
vessel increase significantly as the system is
raised from room temperature to operating tem-
perature. It is necessary to keep the graphite in a
compact array, however, to have control over the
FEBRUARY 1970 195
Bettis and Robertson
MSBR DESIGN AND PERFORMANCE
ntrol Rod Drive
Fig. 4.
TABLE IV
Principle Reactor Design Data for MSBR
Useful heat generation, MW(th)
Gross electrical generation, MW(e)
Net electrical output of plant, MW(e)
Overall plant thermal efficiency, %
Reactor vessel i.d., ft
Vessel height at centerline, ft
Vessel wall thickness, in.
Vessel head thickness, in.
Vessel design pressure, psig
Vessel top flange opening diameter, ft
Core height, ft
Distance across flats of octagonal core, ft
Radial blanket thickness, ft
Graphite reflector thickness, ft
Number of core elements
Size of core elements, in.
Salt-to-graphite ratio in core, % of core volume
Salt-to-graphite ratio in undermoderated region, %
Salt in reflector volume, %
Total weight of graphite in reactor, 1b
Weight of removable core assembly, 1b
Maximum flow velocity in core, ft/sec
Maximum graphite damage flux (>50 keV),
n/(cm? sec)
Graphite temperature in maximum flux region, °F
Average core power density, W/cm?
Maximum thermal neutron flux, n/ (cm2 sec)
Estimated graphite life, yearsa
Pressure drop through reactor due to flow, psi
Total salt volume in primary system, ft®
Thorium inventory, kg
Fissile fuel inventory of reactor system and
processing plant, kg
Breeding ratio
Yield, %/year
Doubling time, years
2250
1035
1000
3.2x 10"
1284
22.2
7.9 x 10%
4
18
1720
68 000
1 468
1.06
3.3
21
“Based on 80% plant factor
196
NUCLEAR APPLICATIONS & TECHNOLOGY
Sectional elevation of MSBR cell complex for 1000 MW (e) power station.
fuel-to-graphite ratios, to ensure that the salt
velocities in the passages are as planned and to
prevent vibration of the graphite. The fact that the
graphite has considerable buoyancy in the fuel
salt, and yet must be supported when the reactor
is empty of salt, is another important design con-
sideration.
Figures 5 and 6 show plan and elevation views
of the reactor. The vessel is ~ 22 ft in diameter
and 20 ft high, with 2-in.-thick Hastelloy-N walls.
The dished heads at the top and bottom are 3 in.