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ORNL-CF-70-9-3.txt
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s 2T T
0 r"l 1'% A
S lu.'.l'-' ~ 3
iy EETES
E A 'J'-I-H'": ".'.
iR § wee®
OAK RIDGE NATIONAL LABORATORY
gy P
e W
OFERATED BY For Internal Use Only
UNION CARBIDE CORPORATION
NUCLEAR DIVISION
2
ORNL <Y
PO S 15 O CENTRAL FILES NUMBER
e SEPO4 WK CF-70-9-3
DATE: September 1, 1970 copyng, 136
SUBJECT: Critique of the Molten-S5alt Reactor Experiment:
A Collection of Comments Submitted by
Persons Associated with the Reactor
TO: Distribution
FROM: R. H. Guymon
ABSTRACT
The MSRE was shut down in December, 1969 after over L years of suc-
cessful operation. As an aid in profiting from the lessons of
the MSRE,
critical comments were solicited from project personnel. There were
28 replies, which are reproduced and summarized in this report,
touching
on practically every phase of the MSRE. Many of the comments are
applicable to other reactors or similar projects that might be
taken.
Keywords: MSRE, reactors, fused salts, critique, design,
under-
development,
construction, training, operation, maintenance, remote maintenance,
personnel, management, communication, documentation, computers.
NOTICE This document contains information of a preliminary nature
and was prepared primarily for internal use at the Oak Ridge
National Laboratory. It is subject to revision or correction and
therefore does not represent a final report. The information is
only for official use and no release to the public shall be made
without the approval of the Legal and Information Contrel Depart-
ment of Union Carbide Corporation, Nuclear Division.
CONTENTS
Introduction « « =« « « « « «
Summary of Contents-
Comments as Received * * = = * =+
Appendix I
A Request for Criticism of the MSRE |
Appendix IT
List of Contributors_
Appendix III
Topical Index . . . . . .
16
82
83
8l
INTRODUCTION
In Janusry 1970, shortly after the MSRE was shut down, a letter was
sent to T6 engineers, chemists, and administrators who had been associated
with the reactor. The letter (a copy of which forms Appendix I) announced
the intention to publish a critique of the MSRE and solicited contribu-
tions. Although contributions were received from less than half of those
contacted, there were many good comments and suggestions which should be
of value to future projects.
In the interests of transmitting their messages unchanged, each of
the 28 replies is reproduced without any editing in one section of this
report. To alid the reader in finding comments on areas of particular
interest, in this section I have indicated in the margin the topic being
discussed in the text. In addition, a topical index is provided as
Appendix III.
As a further aid to the reader I have combined and summarized every-
one's comments. At the end of each paragraph of the summary, I note the
reply and page number where the ideas summarized sare originally expressed.
There were, of course, many duplications among the independent replies,
as may be seen from the multiple references at the ends of some paragraphs.
Additional specific comments and recommendations will be published
in reports on MSRE systems and components1 and on training and operation.2
1
R. H. Guymon, Editor, MSRE System and Components Performance,
USAEC Report ORNL-TM-3039, Oak Ridge National Laboratory, in preparation,
’R. H. Guymon, MSRE Operator Training and Operating Techniques,
USAEC Report, ORNL-TM-3041l, Oak Ridge Natiocnal Laboratory, in preparation.
SUMMARY OF COMMENTS
General
It is hoped that those responsible for various aspects of the molten
salt reactor effort will not only study this critique but also reread the
relevant portions of the progress reports and summary reports and make
the next reactor even better. (M-L9)
The success of the MSRE was enhanced by the ability and dedication
of the perscnnel associated with the project. Management showed their
interest and helped emphasize the importance of the job. (M=-53)(T-68)
Administrative and technical responsibility should be well defined.
Authority should accompany the responsibility. (s-6k)
Cooperation between all groups is a necessary part of successful
ocperation. Their separate interests should be encouraged. For example,
the analysis group should propose any experiment which might supply use-
ful information, the chemists should request samples of any type, and
maintenance should propose short cuts in repairs or modifications. Opera-
tions should review each thoroughly and should be encouraged to be conserva-
tive in order to maintain safe conditions for the protection of personnel
and equipment. (D-25)(M-51)(M-52)
An effort should be made to assure that all involved personnel feel
that they are on the reactor team. This includes the shop foremen, crafts-
men, and remote maintenance personnel. They should be kept informed as to
what is being done and why it is important. (A-16)(A-1T)(T-65)(T-66)
An effort should be made to retain as many of the original personnel
as possible. This includes supervision, operators, foremen, and crafts.
Operators should be on-site early to become familiar with the system and
to follow construction to assure that all systems will operate properly
and to label all equipment when installed. (K- U4l4)(K-L5)(K-LT)
Criteria should be established early and all key personnel should be
thoroughly familiar with them. Limits should be set at reasonable values
with changes made as infrequently as possible. (D-23)(H- 34) (K- 43)(U- 70)
(U-T1)
On a reactor experiment, maximizing reliability should take second
Place to making detalled analysis of the system performance. This applies
to such things as design, taking samples, and varying operating conditions.
(B- 20) (M- 51)
Sufficient instrumentation should be provided so that: (1) detailed
enalysis of the system performance can be made, and (2) the operator does
not have so many jobs that he can not handle them properly. (D-23)(E-26)
(E-27)
There should be considerable improvements in instrumentation and com-
puters on the next reactor due to advancements in the state-of-the-art.
(Q-62) (Q-63) (U-70) (U-T73)
Reactor equipment should be robust and fooclproof and when possible
the design should be such that operation can be done by rotating shift
personnel. Areas requiring more intimate relations between operator and
equipment should be identified early and special operating perscnnel
should be provided. Equipment whose operation is something of an art
should be minimized. (D-25)(I-37)(K-4L)(M-51)(0-5T)
During design, construction, and preparation for operation, all
phases of the operation should be considered. Safety, containment,
shielding, etc., should be adequate during power operations, shutdowns,
and various transient conditions. Advanced plans should be made for de-
commissioning the reactor. (K-U44)(K-L45)(K-L48)
Quality assurance should be given a prominent role in construction
as well as subsequent maintenance and modification. Adequate persocnnel
should be available. Samples of all materials used in construction should
be retained. (E-29)(M-52)(N-55)(T-65)(T-68)
In selecting a supplier, the proper weighting should be given to the
various aspects of the Job so that he will at least be an expert in the
most important phases. (J-38)
Savings of time and money (such as the decision to operate with mar-
ginal amount of flush salt, operating with an oil leak in the fuel pump, or
changing the specification for the fuel-pump motor pressure vessel from
stainless to carbon steel) should be carefully considered. Some prove
costly in the long run. (A-16)(H=-35)(I~36){J-39){(M=54)(U-T0)(W-T6)
When items are used repeatedly such as the sampler transport tubes,
the cost of decontamination should be weighed against the use of low-cost
throwaway items. (I-36)
When repetitive jobs are done (such as removal of graphite specimens
and containment startup check lists) extensive planning should be done to
reduce downtime. (K-L43)(1- L8
Behavior which may appear as a small sideline effect in a development
test should be carefully evaluated for it may become a major problem in
reactor operation. One should not rely on makeshift procedures but
should develop a solution which will work in the reactor. (M-50)
Procedures should be written in advance for checking out instruments
after installation or repairs and for doing maintenance. (K-LL)(K-Lg)
Design
All design calculations should be formally reviewed and reliable data
on the physical properties involved should be available. Thermal stresses
should be carefully considered. (H-34){L-L8)(M-51)(AA-T8)
Detailed design should not be started too early. Title-I design
should be completed before starting Title II and elementary-type drawings
should be issued and approved before detailed drawings are started. (K-43)
(U-70) (Y=-7T)
The use of conventional equipment should be encouraged, however, the
specific application should be carefully evaluated to assure compati-
bility. (H-35)
The design should have some flexibility in the form of spare con-
nections, redundant lines, and open space for additions. With sufficient
redundance and flexibility, it is often possible to circumvent unantici-
pated difficulties. {(M-52)(M-54)(V-75)
The ambient conditions in which equipment and instruments must operate
should be considered in the design. (L-L48)
Absclute instead of gage pressure transmitters should be used where
secondary containment is needed. (U-T73)
Thermocouple wire and other low-level signal wiring should be twisted
and shielded. (U-T3)
The use of a computer for keeping track of control circuit inter-
connecting wiring should be considered. (U-TH4)
When continued operation is critical, spare equipment powered by
separate power sources is recommended. (F-30)
The design of all equipment should be above the shut—off pressure of
the supply (for instance, the design pressure of the thermal shield was
lower than the shut-off pressure of the treated-water pumps). (L-L49)
Keep as much equipment as possible outside of the reactor cell. (Z-78)
To minimize thermal stresses and reduce operator effort, automatic
heater control should be provided. More separate controllers were needed
to get a more even temperature distribution. (D-2L4)(F-33)(N-55)
Documentation
Certain key documents such as the design report, flowsheets, ele-
mentary control circuit drawings, and electricel elementary drawings
should be issued as soon as possible and should te kept up to date
throughout the life of the reactor. (K-39)(K-L0)
Adequate drawings should be issued to supply the needs of all phases
of the project. For instance, construction pecple will be interested in
the pedigree of all material used, types of welds, etc. Exact locations
are often not too important. Remote maintenance personnel are not inter-
ested in the type weld but want to know the exact as-built location of
everything. Overly dimensioned isometrics and photographs would probably
serve their needs best. Both of these can usually afford to spend time
searching for information. On the other hand, operating people need to
know what thermocouples and other instruments are installed, where the
pipes go, etc., and they often need to be able to find this information
quickly. (A-16)(A-18)(A-19)(I-36)(K-L1)
A consistent integrated scheme of documentation should be established.
(K-L42)
Recording of too much information may be cumbersome but it may pre-
vent permanent loss of important data. Errors or mistakes should also be
recorded so that others can profit by them. Field changes should be well
documented. (K-L40)(K-L46) (K-LT)
Training and Operation
In preparation for operation it is important to maintain a list of
all variables with their normal values and limits. The appropriate project-
associated personnel should supply the limits and update these as required.,
This then becomes the basis for the logs and is helpful in writing the
operating procedures. Operating procedures should be written as early as
possible. (XK-LkL)(K-L5)
An operator training manual should be written for use in initial
training and the training of replacement personnel. More use should be
made of simulators and programmed instruction. Graphic panels, the jumper
board, and the model were helpful on the job training aids. Periodic re-
views and tests are recommended. (D-23)(K-L45)(0-56)(K-LT)
The training instructors should be trained in teaching methods. Super-
visors should be trained in the art of supervision. (XK-L46)(X-7T)
Up-to-date operating aids such as flowsheets placed in the various
operating areas were helpful as was having limits marked on heater con-
trollers. (0-56)(0-58)
10
Maintenance
Computerized programmed maintenance of equipment should be carefully
set up and periodically reviewed. (K-47)(V-T7L) -
Remote maintenance supervision and crafts need training early in the
program. (A-16)(A-1T)
Although all required remote maintenance jobs were successfully com-
pleted, hindsight indicates that provisions for this work could have been
better. (A-16)
Provisions should be made for removing equipment from the reactor
cell to a sealed shielded work area without going through the high bay.
Adequate room is needed for doing remote maintenance and areas involved
shou%d be well-ventilated and easily decontaminated. (A-1T)(V-T4)(V-76)
(V-T6)
Since the remote maintenance shield is a key item during shutdowns,
it should be of better quality. A sufficient number of shielded carriers
of all sizes should be available. A contaminated work area should be
provided. (A-17)(V-75)(V-76)(Z2-78)
The number of bolt head sizes used in the cells should be kept at a
minimum and the quality should be improved. (A-18)(V-T5)
Sampling and Analysis
On-site analysis of samples is desirable. As many as possible should
be in-line devices. Flow-through samples are more representative than
dip samples. ©Some specific analytical methods need improving such as
U*/U" and carbon content of the salt and tritium in various gaseous
effluents. (B-20)(B-21)(c-21)(K-47)
Cross contamination of samples should be carefully considered and
sampling mechanisms should be provided at other locations such as the
drain tanks. Efforts should be made to decide ahead of design or con-
struction what type samples will be needed and from where. (B-og)(B-20)
(B-21) (E-28) (I-36) (BB-80)
More consideration should be given to the chemistry of auxiliary
systems. When methods are not available to test for deterioration (such
as the lube o0il for the circulating pumps) periodic replacement should
be made. (F-30)(K-4T)
11
Computer
All reactors should have an on-line computer as at the MSRE. The
reactor design should be compatible with the computer and planning and
programming should start early. (E-27)(M-54)(U-T1)
Reactor engineers should be more closely associated with the computer
and should be trained so that they can participate in the programming of
it and fully utilize its capabilities. ORNL maintenance people should be
trained early. (K-46)(0-57)(Q-60)(Q-61)(Q-62)(Q-63)
During installation and checkout and subsequent maintenance or
trouble-shooting, the computer should be isolated from operating personnel
to avoid loss of confidence in the machine. (Q-61)(Q-61)
On future reactors, some routine control should be delegated to the
computer. The alarm functions should be improved so that important alarms
are not missed or ignored. (D-25)(0-56)(U-71)(U-73)
Noise analysis of all rotating equipment as well as neutron and
pressure noise analysis should be computerized. Proper instrumentation
should be designed for accomplishing this. (E-27)(G-33)
Adequate hardware diagnostic programs should be required of the com-
puter manufacturer. (Q-63)
Chemical Processing
The development and redesign of the fluorine disposal system should
have been done earlier and preferably in another facility. More develop-
ment work is still needed on the use of KOH-KI for removing excess
fluorine. (M-52)(P-59)
Fluorinators should have frozen salt walls or use an alloy not con-
taining molybdenum. (P-59)
All process gas lines leaving shielded areas should contain fibrous
metal filters for remcving metallic fission preducts. (P-60)
12
Miscellaneous
Don't use an existing building. (X-y7)(U-70)(Z-78)
Straight rigid control rods would be simpler and more reliable.
These should be used and placed where they would do the most overall good
even if extra vessel penetrations are necessary. (E-28)
Possible plugging of gas lines should be considered. Better valves
should be developed. The use of more filters is suggested and dual or
larger lines with installed heaters are recommended. (E-29)(F-32)(I-37)
(0-58) (W-76) (U-73) (BB-80)
Salt line penetrations through cell walls require careful design to
prevent plugging. {P-60)
More use should be made of two-out-of-three coincidence leogic to
permit testing and there should be more separation between safety and
control. (U=-T2)
Process radiation and other instruments should be calibrated in terms
which are physically significant. (E-28)
Leak-detected flanges should be replaced with welded pipe using re-
mote welding techniques where possible. Electrical connections in the
cell should be welded to prevent them from coming loose. (F-30)(N-55)
Methods of improvement on the use of freeze valves would be to ele-
vate or pressurize the drain tanks. Two FV's could be used in series with
alternate thawing to increase the life expectancy. Freeze valves made by
spinning INOR-8 pipe might be an improvement. (F-31) (F-32)
It is suggested that a low-speed large diameter pump integral with
the reactor be considered and that cerro alloys be investigated as a re-
placement for the coolant salt. (F-32)
It is suggested that tests be run with the system at negative pressure
to test the effect on fission product stripping. (F-32)
A number of the comments made in the HRE and HRT critiques,,aaL+ are
still applicable. (V-T7L)
3¢. E. Winters, Criticism of the Present Design of the HRE, ORNL-
CF-52-11-139, unpublished internal document, November T, 1952.
*s. E. Beall, Critique of the Homogeneous Reactor Test (HRT) and the
Chemical Plant (HRT-CP), ORNL-CF-61-6-116, unpublished internal document ,
June 1, 1961,
well
13
The holdup time of the charcoal beds appeared to be only about 80%
of the intended value, however, release to the atmosphere was negligible
even when operating with only one bed in service. (BB-79)
The following is a list of items which were thought to have functioned
or are to be recommended.
(a)
Regular on-site planning meetings and communication in
general. (M-53)(T-66)
Cooperation between groups. (D-22)(I-36)
Daily reports. (K-U4T)
The numbering system. (K-43)
Change request system. (M-5L)
Combination heater and thermocouple drawings. (K-L42)
Microfilm drawing reader-printer. (I-37)
Operating procedures. (M-53)
Critical path scheduling of the fabricatiocns of components
and for doing meintenance. (M-54)(T-65)(T-66)
Tdentification and records of material used in construction.
(c-22)(R-63)
Preoperational and precritical testing of equipment. (N-55)
Operator training and reviews. (M-53)(0-56)
Use of a simulator for training. (K-45)(M-53)
All annunciators repeating in the control room. (K-kl)
Location of surveillance specimens. (C-22)(R-64)
Fuel and coolant circuleting pumps. (F-30)(Z-77)
Dust filters on ventilation system inlets. (L-4g)
Instrument maintenance. (D-23)
Seven days continuous operation of the computer before
acceptance. (Q-61)
Design data sheets. (K-L43)
well
(u)
14
The high quality construction used in the cover-gas and offgas
systems. (BB-T79)(BB-80)
The following is a list of items which were thought not to function
or were needed but not supplied.
Drawing index and cross-referencing. (A-16)(K-40)(A~17,19)
A well-organized written description of the control circuits.
(H-35)
Elementary drawings for the safety system, solid-state circuitry,
and the electrical system. (K-Lg)
Thermocouple wells in the fuel salt system. (E-26)(H-34)
Thermocouple wire penetration seals. (U-T3)
Two manipulators at the sampler. (V-75)
Drain tank weigh cells. (E-29)(H-35)
Reactor and drain tank cell reference volumes. (L-48)
Electrosystem temperature modules on freeze valves. (0-59)
Lube o0il system oil cooling. (F-30)
Facilities and storage for remote maintenance., (A-16)(A-17)
(A-17)(I-36)
Vent house remote maintenance. (A-1T7)
Building cranes. (A-18)
Remote maintenance jig and fixture program. (A-18)(Z-77)
A data-plotting board. (D-25)
A fuel salt flowmeter. (E-26)(U-72)
Radiator doors. (M-50)
Check valves. (0-59)
Punched card reader, line printer, and more magnetic tape units
for the computer. (Q-62)
Computer manufacturer's documentation. (Q—61)
Galloping safety circuits. (U-72)
Radiator stack flowmeter. (U-T2)
15
The following is a list of items which were installed and later found
not to be needed.
(a) Automatic load sequencing. (M-52)
(b) Thermocouple patch panel. (D-24) (K-43)
(¢) Helium treatment station. (L-48)(BB-T9)
The thermocouple scanner is the only item on which there was
disegreement. (D-24)(F-33)(U-71)
16
COMMENTS AS RECEIVED
In this section are reproduced verbatim the 28 replies to the
request for criticism of the MSRE. The identity of the writer is given
in Appendix II.
Remote Maint.
Remote Maint.
Organization
Remote Maint.
Documentation
Personnel
Reply A
Remcte Maintenance, or "We Sure Lucked Out on That One"
oomehow or other we were able to fix whatever broke
at the MSRE. Indeed there were times when further operations
depended upon successful completion of rather difficult
remote maintenance operations. However, these operations
were always slow and expensive. Therefore, the comments
that follow do not say that we did it wrong. To the contrary,
I think we did most of it right and well. The gist of what
fcllows says that we could have done it better and that these
points should be considered for the next time.
"Confusion Junction"
The "system used for remote maintenance" was a poorly
organized collection of parts, pecple, and procedures, that
was accorded a rather vague status in the organization of
reactor cperations, and was granted very little authority.
The responsibility, however, was clear and fixed. . '"Be ready
to fix it if it breaks."
Let me elaborate. The personnel involved with a Jjob
involved develcpment, operations, health physics, and craft
people. Information appeared on General Engineering drawings,
Reactor Division drawings, Luther Pugh's MSRE sketches,
Blumberg's and Shugart's sketches and drawings, two volumes
of photographs, and two loose-~leaf books of unpublished
procedures. The equipment to be maintained consisted of
all the equipment in four radicactive cells. The equipment
to do the maintenance was physically scattered all over "the
county." With each job the ground rules changed, although
this stabilized toward the later operations. During the con-
struction and precritical phases I had the definite feeling
that I was not needed and not wanted. This changed after
the reactor went critical. I was needed but still not wanted.
This was borne out by the marked difference in the effort required
to get craft work done between the time that I did remote
maintenance and the second gamma scan. For the latter Jjob
I was "on the team" and things got done very easily.
17
Reply & (Con't)
It is suggested that remote meintenance be made an Qrganization
integral part of the operations group. Remote maintenance
needs to be "on the team."
"Low Budget Productions, Inc."
Many of the decisions which affected my work were
based on "time and money shortages.'" It may be illuminating Remote maint.
if we enumerate some of the things we could have "bought"
had the schedule and budget allowed and then see what benefit
would have been derived. We could have: (1) trained Training
2 or 3 teams such as Shugart and Blumberg, (2) conducted
the P&E craft training program in the precritical period
when we needed it rather than later on, (3) provided better
physical facilities (these are enumerated below in terms
of defects).
The benefit from having provided the above items would
have been shortened downtime for the jobs that were done,
resulting in some cost saving, and a more positive demonstraticn
of the "maintenance capability.'" Further, if the project
had been requested to recover from the hole in the drain
system, and to put the reactor back on line, then an expenditure
such as the above would have been a good investment on
a cost basis.
"Nobody Knows the Facilities I've Seen"
The following is a list of the defects in the equipment
that we had to work with:
1. The vent house was never designed for maintenance Remote Maint.
of the radicactive components located there. There was
no head room, no overhead handling facilities, both the Des - Misc.
permanent and the maintenance shielding were crude, it
was crowded by the beams, pipes, electrical conduits in
the area (Some of these cut down the usable overhead access
area, the room was hard tc decontaminate, and the weather
inside the room was very closely coupled to the weather
outside the room.
2, There were never enough shielded carriers. We Remote Maint.
could have used more, bigger, and better "vitro" shields.
Usually we had to design and fabricate these during the Planning
heat of the shutdown.
3. The high-bay storage rack for remote maintenance
tools was toc small. Other equipment was piled on top Remcte Maint.
of the tools resulting in damage. Neighbors on both ends
Remote Maint.
Management
Des -~ Mech.
Management
Planning
Des - Mech.
Remote Maint.
Management
Remote Maint.
Remote Maint.
Documentation
18
Reply A {Con't)
of the rack moved in and restricted access to the ends
of the rack. A permanent, adequately sized area was promised,
but never delivered. Instead we received wit and humor
such as '"These tools make the high bay look like Big Foots
Used Auto Parts."
h. The portable maintenance shield was a very practical,
hard-working, essential piece of equipment. However, because
of budget restrictions, it was not of good gquality in many
respects. The main bearing was crude which made it hard
to turn. We could have saved set-up time with a system
of jack-screws for leveling the whole unit. Stronger, stiffer
tracks would have been helpful. The light and tool plugs
and penetrations were rough, and made some tool-handling
cperations difficult and time-consuming. The next time
around, this design should be used as a guide, but the
overall quality should be better.
5. Both building cranes were old, and frequently
required repairs, and usually at an inconvenient time.
Most of the trouble was electrical but we also had some
mechanical difficulties with the trailing cables. One
has only to examine the shutdown schedules prepared by
Webster and note how many of the critical jobs involved
either or both the cranes and the portable maintenance
shield, to realize how important reliability and good performance
is for this type of equipment.
6. The bolts used in the cell for remote operations
were poor in the following respects. The head size was
small in relation to the bolt diameter, thus diminishing
the bearing surface. The threads were rough and splintery
and as a result many bolts were discarded. Because the
bolts were expensive, not many were bought. For this reason,
we ran out and had to reorder a number of bolts and this
was expensive. There were at least two cases of galled
bolts in the MSRE cell that had to be removed and replaced
remotely.
T The jig and fixture program turned out to be
non-existent in-so-far as the items we needed to replace
such as the 522 and 523 spoolpieces and venthouse piping.
"The Information May Be on the Drawing —
If You Can Find the Drawing"
The job of remote maintenance involved a large amount
of reactor equipment that was described in the MSRE reactor
drawings. However, the information required for remote
maintenance was not taken into account enough in the preparation
19
Reply A (Con't)
of the drawings. The drawings were complete only in the
aspect that there was enough information to build the reactor.
When one considers maintainability, the following
information is needed.
1. Where is the item located with respect to the
cell block layout.
2. What is in the way or near by.
3. What clearances exist.
4, What does it attach to and how.
5. What does the removable part consist of.
6., What are the envelope dimensions.
7. Finally (although not absolutely necessary) how
is it supposed to be replaced.
While all of the above would make it easier to do Documentation
maintenance or any other drawing research, I would like
to suggest the following minimum steps.
1. Reference drawing numbers and dimensions should
be used liberally on the face of the drawing.
2. A systematic method for going from any detail
tc the next larger assembly and so on and also the reverse
direction should be employed.
3 There should be more liberal use of drawing indexes
and/or picture drawings with the assemblies called out on
them.
"And As the Sun Sinks Behind the Decontamination Facility"
Let me now summarize my opinion on this subject. The
low budget policy was a realistic one, and turned out to Management
be correct. However, had the project been extended for
another fiscal year, it would have been a rather expensive
way to save money. Furthermore, for larger reactors with
their bigger costs and bigger potential hazards, we cannot
afford the luxury of saving time and money at the expense
of maintenance. We must overdesign, overbuild, and overprepare
instead.
Chemistry
Chemistry
Management
Chemistry
Planning
Sampler
20
Reply B
These comments are related to fission product studies,
and are generally related to two kinds of restrietion on
experimental flexibility: inadequate access to regions
and insufficient variation of conditions of chemical interest.
Some of the comments are a result of the slow development
of our understanding, some are related to design inflexibilities,
some to caution and the desire to demonstrate long term
smooth operation, and much to the priorities of other experiments.
As a matter of general philosophy, at some phase of
development of chemical machines, the effects of operation
under chemically extreme conditions should be explored
experimentally. This is preferably done in pilot plants,
such as MSRE or MSBE. This was done in MSRE mostly by
the inadvertent increase in oxidation potential of the
system by means presently subject largely to conjecture,
and the subsequent addition of reductant metals to the
salt to regain the desired though not determinable U®/U"
ratio. Argon replaced helium, purge flow rates were changed,
system flow rate was altered, and modest changes in operating
temperature and pressure were made, though these changes
were mostly organized for physics purposes. However, other
useful variations were not made. These include additions
of gases such as hydrogen, HF, oxygen, water, methane,
and possibly other gases which if added in judicious amounts
to the pump bowl purge could have had very interesting
and informative effects on oxidation potential, oxide behavior,
tritium behavior and other phenomena. To make this effective
would have required good analytical techniques for U3/U*
and tritium analysis (and sampling) among others; these
appear to have been nearly ready when MSRE operation was
stopped.
It was not possible to perform experiments in the
salt other than dipping a few materials in the pump bowl
liquid, and withdrawing for examination. In particular,
no electrodes, nc gas sparging, no filter collection devices
(except magnets) for solids or colloidal materials could
be effectively employed. This was in great part because
the only access was by means of the sampler-enricher system
to the pump bowl. The desired approaches would have been
feasible for an on-site hot cell containing a suitable
flowing salt bypass — admittedly difficult but essential
to the attainment of the data usually firmly stated to
be required.
The only access for fuel and gas samples was within
a spiral spray baffle, with ill-defined salt circulation,
21
Reply B (Con't)
undefined gas circulation, and essentially no possibility
of determining accumulation of materials at the gas liquid
interface. Contamination of sample capsule exteriors by
deposits in the transfer tube is strongly suspected but
poorly defined. Samples of pump bowl salt will represent
circulating selt reliably only for substances certain
to remain in salt during its sprayed passage to the sample
region. Next time, flow-through sample devices as & bypass
on a flowing line, if achievable, will provide samples
far more representative of the flowing salt.
The quality of the gas samples was difficult to assess
for several reasons. Samples were sucked into a capsule
in the space gsbove the pump bowl liquid within the spiral
spray baffle, with varying gas flow down the transfer
tube through this space. Transport conditions and residence
time for gas borne materials are difficult to define for
the pump bowl proper — though presumed "well-mixed" inspite
of baffles — but the gas situation within the spray shield
is even more elusive. Further, the effect of evacuation
of regions containing the seample capsule during removal
procedures is not clear.
The proposed off-gas sample station to have been
attached at the 522 Jjumper line could permit better samples,
but shut down schedules halted fabrication. Even better
would be & suitable flow-through rig capsble of regular
sampling.
Samples were not obtained from the drain tanks —
in particular, some ingrowing 25 Np appears to have been
lost there but periodic samples were not requested to
establish this. Flush salt samples similarly.
Removable metal specimens, in the heat exchanger
inlet and outlet regions for example, could have shed
much light on deposition of corrosion products and fission
products around the system, especially as g function of
altered temperature.
Reply C
One of the more serious deficiencies of the MSRE
was the lack of a routine carbon analysis on the fuel
salt samples taken to monitor corrosion products.
thecretically plus tests out of and in the presence of
irradiation indicated that there were no compatibility
problems under normal MSRE operating conditions. However,
with molten fluoride fuel salt circulating through the
Admittedly,
Chemistry
Planning