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P1152-2038.txt
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[
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P 1152 2038
C
Clo0027
45303
ASPECTS OF MOLTEN FLUORIDES AS HEAT
TRANSFER AGENTS FOR POWER GENERATION
PROEFSCHRIFT
TER VERKRUGING VAN DE GRAAD VAN DOCTOR IN
DE TECHNISCHE WETENSCHAPPEN AAN DE TECHNISCHE
HOGESCHOOL DELFT, OP GEZAG VAN DE RECTOR
MAGNIFICUS PROF. DR. IR. F.J. KIEVITS VOOR EEN
COMMISSIE AANGEWEZEN DOOR HET COLLEGE
VAN DEKANEN, TE VERDEDIGEN OP WOENSDAG
14 FEBRUARI 1979 DES MIDDAGS
OM 13.30 UUR
DOOR
0050827
'-'?.%-) QUELENSTR.IUY <
‘() ’
N4
BAUKE VRIESEMA
werktuigkundig ingenieur S b el
geboren te Uithoorn
Dit proefschrift is goedgekeurd door de promotor
PROF.IR. D. G. H. LATZKO
TABLE OF CONTENTS
LIST OF SYMBOLS
ABSTRACT
1. INTRODUCTION
2. FLOW MEASUREMENTS
2.1. Introduction
2.2. Venturi flow meter
2.2.1. Special features
2.2.2. Description of equipment
2.1. The venturi
2.2. The control system
.2.3. Safety
2.4. Instrumentation
es 24 35 ACCUTACY
2.3. Thermal flow measurement
1. Introductory remarks
Description of the method
a3
P
2.3.3. Description of the equipment
il e dids FEODS
.3.3.2. Electronic output adjustment
2.3.4. Accuracy
2.4. Transit time measurement
1. Introductory remarks
2. Description of the method
.3. Description of equipment
4., Accuracy
2.5. Test program for flow measurements
2.6. Experimental results
2.7. Conclusions
3. TURBULENT HEAT AND MOMENTUM TRANSFER
3.1 Introduction
3.2. Heat transfer
3.2.1. Introductory remarks
3.2.2. Description of the test module
3.2.3. Description of the loop
3.2.4. Outline of the method
3.2.5. Instrumentation
3.2.6. Data reduction and processing
Sedsil « CRIIDTALIiON
3.2.8. Accuracy
3:2:9
Test program
NN
. .
O OO OO0 O U1 LTI WW WN N~ -
N O DDDND DD D N DD DND NN
N N
o .
-
_
N
[EN
O
QL .. Ve 6 L] "
O UTE WNDNNEFE P P
WWwLwwuwwww ww w
K
- 0.5 -
3.2.10. Experimental results
3.2.11. Discussion of results
3.3. Momentum transfer
Introductory remarks
. Description of the method
Description of equipment
.1. Test tube
.2. Differential pressure measurement
Test program
Experimental results
Accuracy
Discussion of results
4. BAYONET TUBE STEAM GENERATOR
4.1,
Introduction
4.1.1. General back-ground
4.1.2. The bayonet tube steam generator
4.1.3. Aims and scope of the present investigations
4.1.2.1. Design characteristics
4.1.2.2. Potential interest
4.1.3.1. Steady state behaviour
4.1.3.2. Dynamic behaviour
4.1.
4.1.
3.2.1. Large transients
3.2.2. Stability
4.2. Basis for analysis
4.2.1. General assumptions
4.2.2. Balance equations
.1. Single-phase flow
.2. Two-phase flow
2.2.1. Thermal equilibrium
2.2.2. Thermal non-equilibrium
4.2.2.3. Energy balance of the wall
4.2.3. Empirical relations
4’
- 0.6 -
4.2.3.1. Transition criteria
=
=
=
=
3
. Te
1.1. Preheat-subcooled
1.2. Subcooled-saturation boiling
.1.3. Saturation boiling-mist flow
1.4. Mist flow-superheat
2. Heat transfer correlations
3. Frictional pressure drop correlations
.4. Slip correlations
5. Heat distribution parameter
st facility
Test module
- = O O WO O~d 9 OO0 (o2 T ® 2 BENN “SEREN SN ) [ J T N ST
L I T S S S S SN i S S S S S S S
o
SN
—
N =
4.12
4.3.1.1. Heating fluid 4.16
4.3.1.2. Flow pattern 4.16
4.3.1.3. Process conditions 4.17
4.3.1.4. Dimensions Rid?
4.3.2. Water/steam loop 4.17
4.3.2.1. General 4.17
4.3.2.2. Feedwater supply system 4.18
4.3.2.3. Heat sink 4.18
4.3.3. Instrumentation and control 4.18
4.3.3.1. Loop instrumentation and control 4.18
4.3.3.2. Test instrumentation 4.19
4.3.3.2.1. Instrumentation for steady state and 4.19
transient experiments
4.3.3.2.2. Instrumentation for the stability experiments 4.20
4.3.3.2.3. Calibration 4.20
4.3.4. Operational procedures 4.21
4.4. Steady state 4.22
4.4.1. Analysis : _ 4,22
4.4.1.1. Additional assumptions 4.22
4.4.1.2. Modified equations 4.23
4.4.1.3. Solutional procedure 4.24
4.4.2. Experiments 4.24
4.4.2.1. Data acquisition 4.24
4.4.2.2. Test program 4.27
4.4.2.3. Experimental results 4.28
.4.3. Evaluation of results 4.28
4.5. Transients 4.28
4.5.1. Introduction 4.28
4.5.2. Analysis 4,29
4.5.2.1. Modified equations 4.29
4.5.2.2. Solution in Eulerian co-ordinates (DYBRU) 4.30
4.5.2.3. Solution in Lagrangian co-ordinates (DSTS) 4.31
4.5.3. Critique of the methods employed 4.33
4.5.4. Experiments 4.34
4.5.4.1. Data acquisition 4.34
4.5.4.2. Test program 4.36
4.5.4.3. Experimental results 4.36
4.5.5. Evaluation of results 4.37
4.5.5.1. Introductory remarks 4.37
4.5.5.2. Comparison of DYBRU with an experiment 4.37
4.5.5.3. Comparison of DSTS with an experiment 4.37
4.6. Stability 4.37
4.6.1. Analysis &.37
in ¢ o R
Introductory remarks
Identification of characteristic sections
> -
N -
. .
4,6.1.2.1. Linearized analysis of the total system
4.6.1.2.2. Linearized description of subsystems
d4.6.1.2.3. Stability criteria
4.6.1.3. Analysis in the time domain
1. Introductory remarks
2. Additional assumptions
.3. Modified equations
4. Solutional procedure
4.6.1.4. Analysis in the frequency domain
1. Extensions in the model
2. Modified equations
.3. Solutional procedure
4. Program structure
4.6.2.1. Introductory remarks
4.6.2.2. Experimental procedure and data acquisition
4.6.2.3. Test program
4.6.3. Evaluation of analytical and experimental results
.1. Introductory remarks
.2. Preliminary program verification in the frequency
domain
.1. Eigenvalue analysis
.2. Frequency analysis
1 MW steam generator experiments
B.6:3.3 +h
4.6.3.3.1. Outline of experiments
4.6.3.3.2. Eigenvalue analysis
4.6.3.3.3. Frequency analysis
4.6.3.4. SWISH experiments
6.3.4.1. Outline of experiments
I
4.
4. .2. Frequency analysis
4.6.3.5. Bayonet tube experiments
6.3.5.1. Time domain analysis
.6.3.5.2. Frequency domain analysis
6.3.5.3. Additional remarks
5. CONCLUSIONS AND RECOMMENDATIONS
ACKNOWLEDGEMENTS
REFERENCES
SAMENVATTING
~J
L S N
. . . .
b W
U1 W N N
P S
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
APPENDIX
2A
3A
4A
4B
4C
4E
4F
4G
4H
4J
4K
Thermal conductivity of FLiNakK
Error analysis of the friction pressure drop
measurement
N\
Energy balances for the subcooled region
An adapted version of the Bankoff-Jones slip
correlation
The derivative of the specific mass of two-phase
mixtureswith respect to the mixture enthalpy
Derivation of the equations describing the
total system
Explanation for the existence of predominant
modes ofparallel channel instability
Zero's of H , and IMI
po
Details of discretization, linearization and
substitution steps in the solutional procedure
res
Example of an application of the SLINQ program
for substitution of linear equations
Power method and vector deflaticn as applied for
determining eigenvalues in the CURSSE program
REFERENCES PERTAINING TO APPENDICES
4A.1
4B.1
4c.1
4E.1
4r.1
4G.1
4H.1
4J.1
4K.1
- 0.9 -
LIST OF SYMBOLS
A = area
= coefficient
C = specific heat
D = diameter
E = mathematical expectation
f = friction factor
g = gravity constant
G = mass flux
h = enthalpy
H = transfer function
Im = imaginary part
K = total conductivity
= heat distribution factor
l1,LL = length
M = mass
Nu = 9X2-= Nusselt number
0 = perimeter
P = pressure
¥ = power
Pr = Prandtl number
q = heat flux
Q = heat flow
= radius
R = covariance function
Re = Reynolds number
= Real part
s = Laplace operator
= slip factor
S = gpectral density function
= time
u = internal energy
v = velocity
w = width
X = steam quality
z = axial co-ordinate
Z = impedance
- 0.10 -~
GREEK SYMBOLS
a = heat transfer coefficient J/m? Oc
= void fraction -
6 = small variation -
= small distance \ m
€ = error &
= angle with upward vertical rad
z = pressure loss coefficient : -
n = dynamic viscosity Ns/m?
6,9 = temperature Oc
A = thermal conductivity J/m Oc
= real part of eigenvalue _ -
o) = gpecific mass kg/m3
T = delay time S
= wall shear stress N/m?
@ = mass flow rate kg/s
= heat flow rate J/s
W = angular velocity rad/s
= imaginary part of eigenvalue -
SUBSCRIBTS
b = bulk
c = correction
= cross-sectional
- o = critical
d = delay
Do = dry-out
E = Eulerian
EV = evaporator channel
f = finish
fl = film
S = friction
FL = FLiNaK channel
g = gas
h = heated
inc = inconel
H = header
= hydraulic
1 = liquid
= lower
= 0.11 -
lg = evaporating
= latent
= Lagrangian
[-1
|
m = mass
= measured
P = pressure
= primary (salt) channel
¥ = released
res = resulting
S = start
= steam
= secondary (water/steam) channel
sat = saturated
t = transferred
tf = two-phase
tot = total
u = upper
v = volume
ve = venturi
7 = wall
MISCELLANEOUS
= average value,
mixture property
maximum value
ABSTRACT
The present thesis consists of two distinct parts. The first of these deals
with the potential application of a molten salt mixture as heat transfer
agent at temperatures well beyond 500 0c. The need for such applications,
which exclude more usual low pressure fluids, may arise from new chemical
processes. The fluid in question, the ternary eutectic of the fluorides of
lithium, sodium and potassium known as FLiNaK, is highly corrosive.
Chapter 2 evaluates three different methods for measuring mass flow rates
of such a corrosive liquid at elevated temperatures, based on venturi, "hot
finger" and transit time techniques, respectively. The evaluation was
performed on pilot plant scale in a molten salt loop.
The same loop was then used to establish empirical correlations for heat
transfer and frictional pressure drop. These experiments, using a salt-to-
air heat exchanger and a calibrated tube respectively, are reported in
Chapter 3 together with the resulting correlations.
The second part of the thesis deals with the thermo-hydraulic performance
of bayonet tube steam generators. The relation with the first part is given
by the fact that this design offers the only possibility for subcritical
steam raising plant heated by FLiNaK or other fluoride mixtures because of
the high melting points of these fluids. The need for such steam raising
plant may result from continued development of molten salt thermal breeder
reactors. For each of the three aspects of thermo-hydraulic design covered
in Chapter 4, viz.:
- steady state behaviour (full and part load)
- transient behaviour
- hydro-dynamic stability,
one or more computer programs were developed and subsequently verified by
comparison with experimental results obtained on a single tube test module
with rated steam conditions of 18 MPa/540 Oc.
In the course of developments in the latter area it became clear that a
continuing need existed for a simulation program capable of predicting
operating limits imposed by either parallel channel or loop instability
for once-through steam generators of various geometries. To that end a
modular user-oriented program (CURSSE) was developed in the frequency
domain and verified by comparison with experimental results obtained both
on the above bayonet tube test module and on two different steam generators
tested elsewhere.
The conclusions for both parts of the thesis as presented in Chapter 5
may be summarized as follows:
® FLiNaK appears well suited as heat transfer agent in the 500 - 700 Oc
temperature range .
bayonet tube design present a technically promising, though perhaps
economically questionable, alternative for raising steam in molten
salt breeder reactor systems
® the CURSSE program was proven a flexible and reliable tool for
predicting the stability limits of once-through steam generators of
various geometries.
- 0.13 -
INTRODUCTION
The research project underlying the present thesis originated in 1963 as a
joint undertaking between Euratom Joint Research Center (Petten
Establishment) and Delft University of Technology, Laboratory for Thermal
Power Engineering. The project's aim was to generate knowledge in the
field of heat transfer by molten fluorides, notably regarding:
® heat transfer and heat transport capability, with special reference
to a ternary eutectic mixture of NaF, LiF and KF further to be
referred to as FLiNak
® the technology of a heat transfer system operating in the 500 - 700 O¢c
temperature range at an semi-industrial ( = pilot plant) scale
® special instrumentation capable of reliable service for prolonged
periods in heat transfer systems such as described in the preceding
paragraph.
The Euratom interest in the development of molten salt technology stemmed
from their potential of these fluids as fuel carrier in fluid fuel nuclear
reactors, as demonstrated by the operation of the 10 MWth Molten Salt
Reactor Experiment (MSRE) at Oak Ridge National Laboratory from 1966 to
1970.
The University's interest was mainly focussed on the second objective
mentioned above, bearing in mind that molten salts constitute one of the
two groups of heat transfer agents capable of operation in the 500 - 700 Oc
temperature range at near atmospheric pressures without chemical stability
problems. The fact that the other group, viz. liquid metals, were already
under extensive study both worldwide and in the Netherlands in connection
with the development of fast breeder reactor cooling systems and the fire
hazard associated with their use suggested the study of molten salts as
potential heat transfer agents in high temperature process plant as a
worthwhile object for a technologically oriented university laboratory.
Continuing development work on the molten salt reactor concept at Oak Ridge
made it increasingly apparent that its eventual transition into the
electric power generating stage would require the solution of a number of
difficult problems in connection with the design of a molten salt heated
steam generator.
These problems are mainly due to the high melting point of the heating
salt, combined with the thermal stress problems inherent to high
temperature liquid systems. With the solution of these problems at Oak
Ridge National Laboratory being delayed by budgetary restrictions the
laboratory for Thermal Power Engineering was presented with an opportunity
for active participation in this area by investigating the so-called
bayonet tube design as a possible solution.
The availability of the FLiNaK primary loop made it possikle to construct a
salt-heated steam generator test facility with relatively little effort.
Feasibility of the bayonet tube steam generator was investigated with
respect to three aspects of the thermo-hydraulic design:
- steady state behaviour at various loads
- transient behaviour
- hydrodynamic stability.
The last two aspects appeared of particular interest because of the
extensive work on steam generator dynamics under way for other projects in
the same laboratory.
The present author's association with the above project further to be
referred to as the Delft Molten Salt Project (DMSP), lasted from August
1969 until its termination in Aprll 1978. Accordingly the work described in
1.1 -
this thesis covers both phases of the project. Investigations concerning
the thermo-hydraulic behaviour of FLiNaK and the associated special
measuring techniques form the subjects of Chapter 2 and 3. Analytical and
experimental investigations of the bayonet tube steam generator thermo-
hydraulics are dealt with in Chapter 4.
Any research report covering a period of over 8 years is liable to
contain parts which are either obsolete by the time of publication and/or
make the author realise in hindsight that a different approach or some
supplementary effort might have yielded better results. The latter is
particularly true in the area of steam generator transient analysis,
where the impending termination of the project foreclosed both additional
experiments and further elaboration of simulation codes. It is the
author's hope that the work reported in this area and some of the analyti-
cal work on steam generator stability may prove of sufficiently general
interest for others to extend and improve upon it.
These aspects which have been studied both analytically by computer
simulations and experimentally in the specially designed single tube test
facility are discussed in Chapter 4.
- 1.2 -
FLOW MEASUREMENTS
Introduction.
The availability of a suitable flow measuring device is essential for the
application of any fluid as an industrial heat transfer agent. For most
fluids differential pressure type flow meters (e.g. using a venturi-type
restriction) are entirely adequate; with this type of device a vast amount
of industrial experience has been accumulated over many years.
However, in the case of molten fluorides and similar high melting salts the
very high temperature level (500 - 700 Oc) and the corrosivity of the fluid
exclude the application of such standard flow meters.
Fluids posing similar problems are:
- toxic fluids
- corrosive liquids (acids)
- liquid metals (e.g. sodium)
Especially in the latter case the problems are very similar to those for
molten salts, and considerable efforts have been made for their solution
within the framework of LMFBR development activities.
However, unfortunately for the project under discussion, by far the largest
and most successful part of these efforts has gone into the development of
electromagnetic devices. In these devices a magnetic field is induced in
the flowing liquid at right angles to the magnetic field and to the velo-
CLtY. ;
To pick up this e.m.f. two electrodes are provided in the wall of the tube.
Unless the resistivity of the fluid approximates that of the pipe wall
material, as is the case for liquid metals, the electrodes have to be
electrically insulated from the pipe wall. Up till now no insulated elec-
trodes are available that are leaktight at the molten salt operating
temperature level, thereby excluding application of this method in molten
salt systems.
Of the other flow measuring systems considered by the author the following
two seemed most promising for this latter application:
- transit time flow meter
- thermal flow meter
Their advantages and disadvantages are discussed in detail in TURNER
[2.1-1 ]. In the following only their potential for molten salt flow
measurement will be taken into consideration.
On the other hand it was evident that of the two parts making up a diffe-
rential flow meter, viz.
- the restriction causing the pressure differential
- the differential pressure measurement
only the latter gives rise to serious problems for the application
envisaged here.
Thus two alternative and complementary roads towards a practical and
reliable flow measuring device seemed open to the author:
- development of a diffential pressure transmitter suitable for molten
salts; in practice this meant transforming the pressure of the salt into
that of an other fluid of easier handling characteristics
- investigation of the other measuring principles mentioned above.
The former approach, in addition to adhering to normal industrial practice,
has the major advantage of offering the possibility for reliable analytical
determination of its characteristics, so that calibration of the flow meter
- 2.1 -
13 unnecessary unless a very high accuracy is needed (better than 2%, which
is the maximum accuracy that can be obtained for a venturi, manufactured in
accordance with the V.D.I. DURCHFLUSZMESZREGELN [ 2.2-2 ]).
Where calibration is required, the results obtained in a water system can
be converted for application in any fluid, including molten salts.
On the other hand, transit time flow meters offer the potential of high
long term reliability through a minimum of equipment in the molten salt
environment, while the thermal flow meter, in addition to being also a
relatively simple device, would capatalize on the heat transfer measurement
techniques extensively investigated in the remainder of the project.
Hence both roads were pursued; the results are described in the next
sections.
2.2. Venturi flow meter.
2.2.1. Special features.
The principle of measuring flows through pressure differences across
orifices such as venturi tubes has been successfully applied in industrial
practice for many years. The discussion in the present thesis will there-
fore be restricted to the special features resulting from its application
to molten fluorides at up to 700 Oc.
The high temperature and the corrosivity of the salt make it impossible to
fill the piping to the differential pressure transmitter and the trans-
mitter itself with the fluid to be measured, as is customary in venturi
liquid flow measurements.
This problem can be solved by the application of an intermediate system
filled with a different fluid of easier handling characteristics between
the venturi and the differential pressure meter. _
One possibility is the use of a liquid, separated from the salt by a
membrane. This fluid has to be proof against the operating temperature and
should preferably be in the liquid state at room temperature.
This approach, shown in figure 2.2-1, has been tested in the Oak Ridge
National Laboratory using NaK as intermediate fluid (cf. BRIGGS [2.2.1]).
There are, however, a number of disadvantages to this all-welded design:
- while the dP-meter can be of standard design, it has to be specially
fabricated and filled with Nak
- calibration after installation is not possible
- the instrument proved rather sensitive to temperature changes in the
system
- in case of breakdown replacement of the dP-meter is difficult.
The major advantage of the all-welded design is its complete leaktightness.
An other possibility is the use of a gas as intermediate fluid. This
system was tested in our laboratory. To transform salt pressure into gas
pressure use is made of two small vessels between the venturi and the
differential pressure transmitter, each connected to one of the pressure
taps of the venturi. In these vessels the FLiNaK level is kept at a con-
stant height by adjusting the cover gas (argon) supply to - or release
from - the gas-filled space (cf. figure 2.2-2).
The resulting cover gas pressure difference between the two vessels is the
same as the pressure difference across the two venturi taps.
This transforms the problem of measuring the molten salt pressure differen-
tial into the much simpler one of measuring a differential gas pressure.
- 2o =
2.2.2. Description of equipment.
2.2.2.1. The venturi.
The venturi itself was designed and machined according to the V.D.I.
DURCHFLUSZMESZREGELN [ 2.2-2 ] (cf. figure 2.2-3).
Normally such a venturi does not require calibration. In this case, however,
the dimensions were somewhat below the normal DIN range and a calibration
was therefore considered necessary.
This calibration, performed by the staff of the "Waterloopkundig Laborato-
rium Delft" (VERBEEK [ 2.2-3 ]) using water as the working fluid, resulted
in the following characteristic formula:
<3
¢m = . 1.45% 10, o &p p'£3.2% ku/s (2.2-1)
(Ap in N/m2, p in kg/m3)
The accuracy stated above resulted from the calibration and is valid for
Re-numbers over 1.4 x 10%.
The Re-number for FLiNaK in this venturi in the range of interest is given
in figure 2.2-4 as a function of mass flow and temperature.
2.2.2.2. The control system.
As stated in subsection 2.2-1 the method requires equalization of the salt
levels in the two expansion vessels by adjusting the cover gas pressures
where required.
While it would be sufficient to maintain both levels at the same (varying)
height, this is more difficult to achieve in practice than to keep them
both constant.
Because of the problems encountered in designing a level gauge capable of
continuous level measurement, the idea of applying a continuous control
system was abandoned in favour of a simple on-off control system.
Two alternative control systems based on the above method of level detec-
tion were successively tested. .
The second and final system will be described first. In this system (cf.
schematic diagram figure 2.2-5) the level is detected by three electrodes
making or breaking contact with the fluid in the expansion vessels. These
electrodes are mounted in the upper part of the expansion vessels by means
of a gastight ceramic insulation (figure 2.2-6).
By measuring the electric resistance between the electrode and the vessel
it is possible to detect whether the salt level is above or below the tip
of the electrode.
If the level rises and passes the tip, contact is made and the electrical
resistance drops to a very low value. However, if the level falls and
passes the tip of the electrode contact is maintained until the liquid
column developing under the electrode as a result of capillary forces
(figure 2.2-7) collapses. The maximum height of this FLiNaK column was
found to be about 2.5 mm for an electrode with a flat tip, decreasing as
the tip of the electrode is sharpened. This phenomenon introduces a sort of
dead band in the action of the electrode.
The shortest electrode forms no part of the control, but is part of the
safety system, to be discussed in the next section.
The other two electrodes define a discrete interval in height within which
the level is maintened by the control system. If the level rises above the
tip of the shorter electrode gas is supplied to the gas-filled space in the
- 2.3 -
expansion vessel, thus driving the level down again until contact is broken.
On the other hand, if the level falls below the tip of the longer electrode,
gas is released from the vessel to allow the level to rise again until
contact is re-established.
Under steady state conditions the level remains in the interval between the
ends of the electrodes without any action of the control system; fluctuati-
ons within this interval are discernible as ripples in the output signal of
the flowmeter, as e.g. in figure 2.2-8, showing a change in flow from one
steady state value to another and the reactions of the control system.
The control system described above was developed from an earlier version,
originally thought to be simpler amd more accurate. In that system each
vessel contained only one control electrode (schematic diagram figure
2.2-9). During operation gas was released from the vessels at a constant
rate. If the salt level rose so high that contact was made with the elec-
trode, gas was supplied at a rate exceeding the release rate, thus driving
down the level. As in the previous system the salt column under the elec-
trode introduced a dead band in the system's reaction.
This seemingly simpler system was found to possess a number of
disadvantages:
® although for steady state conditions the maximum deviation of the
level equals the maximum height of the salt column, much greater
deviations could occur under dynamic conditions without being
recognized as excessive by the control system.