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[Example] Add TADF材料分子的光电性质预测 #974
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Thanks for your contribution! |
请起一个合适的标题 @YfB1125 ,并补充一下PR的简单描述 |
commit代码之前请安装pre-commit,并且使用pre-commit格式化代码,否则code-style-check CI无法通过 |
辛苦把案例文档放到example里并且安装文档的相关要求对案例文档做一下修正吧(https://paddlescience-docs.readthedocs.io/zh-cn/latest/zh/development/#31) |
TADF案例请移动到examples里的位置 |
辛苦尽快修改一下代码或者提交新的PR |
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TADF材料分子的光电性质预测
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有机发光二极管(OLED)具有高效率、结构灵活和低成本的优势,在先进显示和照明技术中受到广泛关注。在有机发光二极管器件中,电注入载流子以1:3的比例形成单线态和三线态激子。以纯荧光材料为发光材料构建的OLED发光效率IQE理论极限为25%。另一方面,有机金属复合物发光材料通过引入稀有金属(Ir,Pt等)带来强自旋轨道耦合(SOC),可以将单线态激子通过系间窜越过程转化成三线态激子,从而利用三线态激子发出磷光,其IQE可达100%,但是稀有金属价格昂贵,为推广使用带来了阻碍。热活化延迟荧光材料(TADF)为解决这些问题提供了新思路,并引起了广泛关注。在TADF中,三线态通过逆系间窜越过程(RISC)转化成单重态并发出荧光,从而实现100%的IQE,而RISC过程很大程度上取决于最低单线态(S1)和最低三线态(T1) 之间的能隙(ΔEST)。根据量子力学理论,ΔEST相当于HOMO和LUMO之间的交换积分的两倍。因此TADF分子的常见设计策略是将电子供体(D)和电子受体(A)以明显扭曲的二面角结合以实现HOMO和LUMO在空间上明显的分离。然而,与ΔEST相反,振子强度(f)需要较大的HOMO和LUMO之间的重叠积分,这二者之间的矛盾需要进一步平衡。